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Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery

文献类型：期刊论文

作者Yang, Zhenzhen1,2; Xiao, Ru2,3; Zhang, Xiaoyin2,3; Wang, Xin1,2; Zhang, Dong1,2; Sun, Zhenhua2,3; Li, Feng2,3
刊名ENERGY & ENVIRONMENTAL MATERIALS
出版日期2021-08-22
页码18
关键词adsorption capacity catalytic materials reaction kinetics room temperature sodium-sulfur battery
DOI10.1002/eem2.12224
通讯作者Zhang, Dong(dongzhang@jlu.edu.cn) ; Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
英文摘要Room temperature sodium-sulfur (RT Na-S) battery with high theoretical energy density and low cost has spurred tremendous interest, which is recognized as an ideal candidate for large-scale energy storage applications. However, serious sodium polysulfide shutting and sluggish reaction kinetics lead to rapid capacity decay and poor Coulombic efficiency. Recently, catalytic materials capable of adsorbing and catalyzing the conversion of polysulfides are profiled as a promising method to improve electrochemical performance. In this review, the research progress is summarized that the application of catalytic materials in RT Na-S battery. For the role of catalyst on the conversion of sulfur species, specific attention is focused on the influence factors of reaction rate during different redox processes. Various catalytic materials based on lightweight and high conductive carbon materials, including heteroatom-doped carbon, metals and metal compounds, single-atom and heterostructure, promote the reaction kinetic via lowered energy barrier and accelerated charge transfer. Additionally, the adsorption capacity of the catalytic materials is the key to the catalytic effect. Particular attention to the interaction between polysulfides and sulfur host materials is necessary for the exploration of catalytic mechanism. Lastly, the challenges and outlooks toward the desired design of efficient catalytic materials for RT Na-S battery are discussed.
资助项目National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; National Natural Science Foundation of China[51902316] ; National Natural Science Foundation of China[51525206] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; LiaoNing Revitalization Talents Program[XLYC1908015] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Special Projects of the Central Government in Guidance of Local Science and Technology Development[2020JH6/10500024]
WOS研究方向Materials Science
语种英语
出版者WILEY
WOS记录号WOS:000687087000001
资助机构National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Special Projects of the Central Government in Guidance of Local Science and Technology Development
源URL[http://ir.imr.ac.cn/handle/321006/159289]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhang, Dong; Sun, Zhenhua; Li, Feng
作者单位1.Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Battery, Minist Educ, Changchun 130012, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714		 Yang, Zhenzhen,Xiao, Ru,Zhang, Xiaoyin,et al. Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery[J]. ENERGY & ENVIRONMENTAL MATERIALS,2021:18.
APA Yang, Zhenzhen.,Xiao, Ru.,Zhang, Xiaoyin.,Wang, Xin.,Zhang, Dong.,...&Li, Feng.(2021).Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery.ENERGY & ENVIRONMENTAL MATERIALS,18.
MLA Yang, Zhenzhen,et al."Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery".ENERGY & ENVIRONMENTAL MATERIALS (2021):18.

入库方式： OAI收割

来源：金属研究所

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