Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol
文献类型：期刊论文
| 作者 | Lv, Lin1; Wang, Yongzhao2; Peng, Dengchao1; Zhou, Zhiyuan1; Shang, Jing1; Guo, Wenyao1; Zhang, Bingsen2; Xin, Zhiling1 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2021-08-06 |
| 卷号 | 6期号:29页码:7384-7390 |
| 关键词 | Benzyl alcohol Layered Co(OH)(2) Oxidation Pd nanoparticles Supported catalysts |
| ISSN号 | 2365-6549 |
| DOI | 10.1002/slct.202101673 |
| 通讯作者 | Guo, Wenyao(guowenyao@shiep.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Xin, Zhiling(xinzhiling@126.com) |
| 英文摘要 | In this work, two-dimensional (2D) Co(OH)(2) nanosheets, with large surface areas and wrinkles are obtained, and used to support Pd nanoparticles (NPs) by simple impregnation method as an efficient catalyst for the oxidation of benzyl alcohol under solvent-free conditions. The resulting 1 wt.% Pd/Co(OH)(2) catalyst exhibits a high turnover frequency value of 57999 h(-1). The catalysts were characterized by SEM, TEM, AFM, XRD, BET, XPS and CO-pulse chemisorption. The results of characterizations reveal that the Pd NPs are highly dispersed on the Co(OH)(2) nanosheets. The abundant hydroxyl groups on the surface of Co(OH)(2) nanosheets promote the reduction of Pd species, resulting in a higher proportion of Pd-0 than that of Pd/AC catalyst, which further facilitates the catalytic performances. |
| 资助项目 | National Natural Science Foundation of China[21773269] ; Liao Ning Revitalization Talents Program[XLYC1807175] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000680162200016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Liao Ning Revitalization Talents Program |
| 源URL | [http://ir.imr.ac.cn/handle/321006/159312]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Guo, Wenyao; Zhang, Bingsen; Xin, Zhiling |
| 作者单位 | 1.Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Lin,Wang, Yongzhao,Peng, Dengchao,et al. Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol[J]. CHEMISTRYSELECT,2021,6(29):7384-7390. |
| APA | Lv, Lin.,Wang, Yongzhao.,Peng, Dengchao.,Zhou, Zhiyuan.,Shang, Jing.,...&Xin, Zhiling.(2021).Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol.CHEMISTRYSELECT,6(29),7384-7390. |
| MLA | Lv, Lin,et al."Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol".CHEMISTRYSELECT 6.29(2021):7384-7390. |
入库方式： OAI收割
来源：金属研究所
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