Effects of LaB6 on the high-temperature oxidation behavior of TiC+TiBx reinforced titanium matrix composite coatings fabricated by laser cladding
文献类型:期刊论文
作者 | Yin, Xiuyuan1; Liang, Jing1; Gao, Yunfei1; Lin, Ziyang1; Chen, Suiyuan1; Liu, Changsheng1; Tian, Kun2; Zhang, Hongwei3; Tang, Guangquan3 |
刊名 | SURFACE & COATINGS TECHNOLOGY
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出版日期 | 2021-09-15 |
卷号 | 421页码:12 |
关键词 | LaB6 Laser cladding Composite coatings Oxidation behavior Microstructure |
ISSN号 | 0257-8972 |
DOI | 10.1016/j.surfcoat.2021.127445 |
通讯作者 | Liang, Jing(liangj@atm.neu.edu.cn) |
英文摘要 | The effects of LaB6 addition on the oxidation behavior of TiC+TiBx reinforced titanium matrix composite coatings at the temperature of 600 degrees C were investigated. The results showed that severe oxidation occurred on the Ti-6Al-4V after oxidation at 600 degrees C for 50 h. The oxidation weight gain of the (TiC+TiBx)/Ti coating without LaB6 addition (2.43 mg/cm(2)) was reduced to 49.6% that of the Ti-6Al-4V substrate (4.9 mg/cm(2)). Though (TiC+TiBx)/Ti coatings improved the oxidation resistance for the surface of Ti-6Al-4V substrates, cracks were easily formed between the coarse rod-like TiB2 and the titanium matrix during the high temperature resulting in less high-temperature oxidation protection. When the LaB6 addition gradually increased from 0 wt% to 1.0 wt%, the oxidation weight gain decreased from 2.43 mg/cm(2) to 1.30 mg/cm(2), and the linear rate constant K-p1 decreased from 0.04752 to 0.02703. The oxidation law gradually changed from the linear law to the parabolic law when the LaB6 addition increased to 1.5 wt%, which indicated the oxide layer gradually became dense and protective. The oxidation weight gain decreased from 1.23 mg/cm(2) to 0.87 mg/cm(2) when the LaB6 addition increased from 1.5 wt% to 2.0 wt%, while increased instead when the LaB6 addition increased to 2.5 wt%. An appropriate amount of LaB6 (2.0 wt%) addition significantly improved the oxidation resistance of the coating with the lowest parabolic velocity constant K-p2 = 0.01418 due to the refinement of grain sizes of the coating, especially the refinement of the coarse rod-like TiB2 phase, which decreased the crack forming sensibility and increased the compactness and continuity of the oxidation layer. A small amount of in-situ formatted La2O3 at the grain boundaries acted as a barrier also blocked the ingress of oxygen. |
资助项目 | National Key Research and Development Program of China[2016YFB1100203] ; NSFC-Liaoning[U1508213] ; NSFC[51201030] ; Key R&D Projects in Liaoning Province[2020JH2/10100022] |
WOS研究方向 | Materials Science ; Physics |
语种 | 英语 |
WOS记录号 | WOS:000681716300022 |
出版者 | ELSEVIER SCIENCE SA |
资助机构 | National Key Research and Development Program of China ; NSFC-Liaoning ; NSFC ; Key R&D Projects in Liaoning Province |
源URL | [http://ir.imr.ac.cn/handle/321006/159315] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Liang, Jing |
作者单位 | 1.Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat, Key Lab Addit Mfg & Remfg Mat,Minist Educ, Shenyang 110819, Liaoning, Peoples R China 2.Shenyang Ruixian Intelligent Equipment Technol Co, Shenyang, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Yin, Xiuyuan,Liang, Jing,Gao, Yunfei,et al. Effects of LaB6 on the high-temperature oxidation behavior of TiC+TiBx reinforced titanium matrix composite coatings fabricated by laser cladding[J]. SURFACE & COATINGS TECHNOLOGY,2021,421:12. |
APA | Yin, Xiuyuan.,Liang, Jing.,Gao, Yunfei.,Lin, Ziyang.,Chen, Suiyuan.,...&Tang, Guangquan.(2021).Effects of LaB6 on the high-temperature oxidation behavior of TiC+TiBx reinforced titanium matrix composite coatings fabricated by laser cladding.SURFACE & COATINGS TECHNOLOGY,421,12. |
MLA | Yin, Xiuyuan,et al."Effects of LaB6 on the high-temperature oxidation behavior of TiC+TiBx reinforced titanium matrix composite coatings fabricated by laser cladding".SURFACE & COATINGS TECHNOLOGY 421(2021):12. |
入库方式: OAI收割
来源:金属研究所
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