Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes
文献类型：期刊论文
| 作者 | Lu, Zhuo-Qun1; Zhang, Lan-Lan1; Yan, Yukun2; Wang, Wei1 |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2021-07-27 |
| 卷号 | 54期号:14页码:6891-6900 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/acs.macromol.1c00783 |
| 通讯作者 | Wang, Wei(weiwang@nankai.edu.cn) |
| 英文摘要 | Hybrid polyelectrolytes comprising a polynorbornene backbone and pendant polyoxometalate (POM) groups, with different degrees of polymerization (DP = 100, 200, and 400), are described. The tetrabutylammonium counterions associated with the POM [(P2V3W15O62)(9-); molecular weight = 3964 Da] groups were exchanged for protons and alkali-metal cations by two cation-exchange methods, without breaking the covalent bond between the POM cluster and the polymer chain. The structural integrity of the POM clusters, which is maintained in anionic polyelectrolytes with ionization numbers ranging from 1.1-4.8 to above six, enables their combination with chiral organic cations to induce chiroptical activity in POMs and with polycations to form polyelectrolyte complexes. We compared the ionization behavior of POM polyelectrolytes with those of POM hybrids and inorganic POM clusters. POM polyelectrolytes have promising applications in electrochemistry, catalysis, and materials science, as well as in electrochromic and photochromic devices. |
| 资助项目 | National Natural Science Foundation of China[NSFC 92061120] |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000679398200027 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/159681]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Wang, Wei |
| 作者单位 | 1.Nankai Univ, Inst Polymer Chem, Ctr Synthet Soft Mat, Minist Educ,Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,et al. Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes[J]. MACROMOLECULES,2021,54(14):6891-6900. |
| APA | Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,&Wang, Wei.(2021).Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes.MACROMOLECULES,54(14),6891-6900. |
| MLA | Lu, Zhuo-Qun,et al."Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes".MACROMOLECULES 54.14(2021):6891-6900. |
入库方式： OAI收割
来源：金属研究所
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