Facile Preparation of CeO2 Supported on Graphene Oxide Sheets for NH3-SCR: Improvement of Catalytic Activity and SO2 Tolerance
文献类型：期刊论文
| 作者 | Zhou, Zhiyuan2; Wang, Yongzhao3; Yuan, Qunfu2; Guo, Yanle2; Guo, Wenyao2; Xin, Zhiling2; Zhang, Bingsen3; Guo, Ruitang1 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2021-05-20 |
| 卷号 | 6期号:19页码:4859-4865 |
| ISSN号 | 2365-6549 |
| 关键词 | CeO2 NH3-SCR Nitrogen oxide Graphene oxide SO2 tolerance |
| DOI | 10.1002/slct.202101102 |
| 通讯作者 | Xin, Zhiling(xinzhiling@126.com) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Guo, Ruitang(grta@zju.edu.cn) |
| 英文摘要 | In this paper, a series of highly dispersed CeO2 catalysts on graphene oxide sheets (GO) were prepared by simple impregnation method. The catalysts were applied for selective catalytic reduction(SCR) of NO with NH3. Compared with the 5 wt %CeO2/GO and 15 wt %CeO2/GO catalysts, 10 wt %CeO2/GO catalyst exhibited better catalytic performance in the temperature range of 175-325 degrees C and higher SO2 resistance at 275 degrees C. The as-prepared catalysts were characterized by TEM, AFM, XPS, XRD, BET, H-2-TPR, NH3-TPD and FT-IR, respectively. The characterization results indicated that 10 wt %CeO2/GO catalyst possessed larger specific surface area, enriched surface acidic sites, high redox capacity and oxygen vacancies. In addition, Ce3+ on the surface of CeO2/GO catalyst could reduce the oxidation property of SO2, thus improving the SO2 resistance of the catalyst. Meanwhile, the stability of 10 wt %CeO2/GO catalyst was tested. At 275 degrees C, the NO conversion maintained at 94 % within 30 hours, suggesting the excellent stability. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000656866400023 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/160383]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xin, Zhiling; Zhang, Bingsen; Guo, Ruitang |
| 作者单位 | 1.Shanghai Univ Elect Power, Shanghai Engn Res Ctr Power Generat Environm Prot, Shanghai, Peoples R China 2.Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Zhiyuan,Wang, Yongzhao,Yuan, Qunfu,et al. Facile Preparation of CeO2 Supported on Graphene Oxide Sheets for NH3-SCR: Improvement of Catalytic Activity and SO2 Tolerance[J]. CHEMISTRYSELECT,2021,6(19):4859-4865. |
| APA | Zhou, Zhiyuan.,Wang, Yongzhao.,Yuan, Qunfu.,Guo, Yanle.,Guo, Wenyao.,...&Guo, Ruitang.(2021).Facile Preparation of CeO2 Supported on Graphene Oxide Sheets for NH3-SCR: Improvement of Catalytic Activity and SO2 Tolerance.CHEMISTRYSELECT,6(19),4859-4865. |
| MLA | Zhou, Zhiyuan,et al."Facile Preparation of CeO2 Supported on Graphene Oxide Sheets for NH3-SCR: Improvement of Catalytic Activity and SO2 Tolerance".CHEMISTRYSELECT 6.19(2021):4859-4865. |
入库方式： OAI收割
来源：金属研究所
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