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Na-CO2 battery with NASICON-structured solid-state electrolyte

文献类型：期刊论文

作者Tong, Zizheng2; Wang, Shu-Bo2; Fang, Mu-Huai2; Lin, Yen-Ting2; Tsai, Kun-Ta1; Tsai, Sung-Yu1; Yin, Li-Chang3; Hu, Shu-Fen4; Liu, Ru-Shi2
刊名NANO ENERGY
出版日期2021-07-01
卷号85页码:9
ISSN号2211-2855
关键词Solid-state Na-CO2 battery NASICON NZSP Solid-state battery Na-metal battery
DOI10.1016/j.nanoen.2021.105972
通讯作者Yin, Li-Chang(lcyin@imr.ac.cn) ; Hu, Shu-Fen(sfhu.hu@ntnu.edu.tw) ; Liu, Ru-Shi(rsliu@ntu.edu.tw)
英文摘要Utilizing CO2 as cathode gas, Na-CO2 battery has been intensively studied due to its potential application in the exploration of Mars, where CO2 takes up 96% of the atmosphere. However, evaporation of the flammable liquid electrolyte restricts the practical application of the Na-CO2 battery. Herein, a solid-state Na-CO2 battery has been fabricated with the help of a plastic crystal electrolyte and kinetically stable interphase. The succinonitrilebased plastic crystal electrolyte interphase makes an intimate contact between Na3Zr2Si2PO12(NZSP) and cathode, thereby promotes the interfacial charge transfer. Simultaneously, the kinetically stable interphase on the anode side is revealed by the cooperation of theoretical calculation and experiments. The kinetically stable interphase protects the NZSP from the continuous interfacial parasitic reaction. The as-proposed solid-state Na-CO2 battery delivers a life span of 50 cycles at 100 mA g(-1) with a potential gap of 1.4 V. This study makes solid-state electrolyte Na-CO2 battery an attractive prospect in future applications.
资助项目Ministry of Science and Technology (MOST) of Taiwan[MOST 109-2113-M-002-020-MY3] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 109-2112-M-003-011] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 107-2113-M-002-008-MY3] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 106-2112-M-003-007-MY3] ; National Natural Science Foundation of China (NSFC)[51972312] ; National Natural Science Foundation of China (NSFC)[51472249]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者ELSEVIER
WOS记录号WOS:000663443300002
资助机构Ministry of Science and Technology (MOST) of Taiwan ; National Natural Science Foundation of China (NSFC)
源URL[http://ir.imr.ac.cn/handle/321006/160515]  
专题金属研究所_中国科学院金属研究所
通讯作者Yin, Li-Chang; Hu, Shu-Fen; Liu, Ru-Shi
作者单位1.China Glaze Co Ltd, 136,Sect 4,Chung Hsing Rd, Hsinchu 31061, Taiwan
2.Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
4.Natl Taiwan Normal Univ, Dept Phys, Taipei 116, Taiwan
推荐引用方式
GB/T 7714		 Tong, Zizheng,Wang, Shu-Bo,Fang, Mu-Huai,et al. Na-CO2 battery with NASICON-structured solid-state electrolyte[J]. NANO ENERGY,2021,85:9.
APA Tong, Zizheng.,Wang, Shu-Bo.,Fang, Mu-Huai.,Lin, Yen-Ting.,Tsai, Kun-Ta.,...&Liu, Ru-Shi.(2021).Na-CO2 battery with NASICON-structured solid-state electrolyte.NANO ENERGY,85,9.
MLA Tong, Zizheng,et al."Na-CO2 battery with NASICON-structured solid-state electrolyte".NANO ENERGY 85(2021):9.

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来源：金属研究所

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