中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Improvement of electrochemical performance of Mn-Fe based

文献类型:期刊论文

作者Su, Chang1; Liu, Guoqiang1,2; Gao, Yibo1; Zhang, Yixuan1; Wen, Lei3
刊名JOURNAL OF ALLOYS AND COMPOUNDS
出版日期2021-10-15
卷号878页码:12
关键词Sodium ion batteries Cathode materials Mn-Fe based layered oxide Mg doping Electrochemical properties
ISSN号0925-8388
DOI10.1016/j.jallcom.2021.160427
通讯作者Liu, Guoqiang(liugq@smm.neu.edu.cn) ; Wen, Lei(leiwen@imr.ac.cn)
英文摘要This work focused on the improvement on the electrochemical properties of the Mn-Fe based layered oxide materials as cathode for sodium ion batteries. The strategy of substituting Mn by cheap Mg element is studied in detail. The influences of Mg content on the crystal structure and electrochemical properties are investigated by XRD and charge-discharge tests, respectively. The composition with the most optimum Mg content is determined as Na0.69Mn0.82Fe0.08Mg0.1O2. It exhibits improved performance compared with previously reported literature. Its initial discharge capacity reached 175.8 mAh g-1 at a current density of 20 mA g-1. Meanwhile, it displays much better rate capabilities with a capacity retention as high as 71.6% after 100 cycles at a higher current rate of 100 mA g-1. More significantly, it can deliver high discharge capacities of 121, 102, and 91 mAh g & minus;1 at high current densities of 400, 1000, and 2000 mA g-1, respectively. (c) 2021 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51574081]
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000660477400006
出版者ELSEVIER SCIENCE SA
资助机构National Natural Science Foundation of China
源URL[http://ir.imr.ac.cn/handle/321006/160656]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Guoqiang; Wen, Lei
作者单位1.Northeastern Univ, Sch Met, Minist Educ, Key Lab Ecol Met Multimetall Mineral, Shenyang 110819, Liaoning, Peoples R China
2.Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Su, Chang,Liu, Guoqiang,Gao, Yibo,et al. Improvement of electrochemical performance of Mn-Fe based[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,878:12.
APA Su, Chang,Liu, Guoqiang,Gao, Yibo,Zhang, Yixuan,&Wen, Lei.(2021).Improvement of electrochemical performance of Mn-Fe based.JOURNAL OF ALLOYS AND COMPOUNDS,878,12.
MLA Su, Chang,et al."Improvement of electrochemical performance of Mn-Fe based".JOURNAL OF ALLOYS AND COMPOUNDS 878(2021):12.

入库方式: OAI收割

来源:金属研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。