Electrochemical and surface analytical studies of transition metal bipyridine dicarboxylic acid complexes as corrosion inhibitors for a mild steel in HCl solution
文献类型:期刊论文
作者 | Liu, Xia1; Sun, Yue1; Lu, Meiheng1,3; Pan, Xuemei1; Wang, Zhengbin2 |
刊名 | JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
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出版日期 | 2021-05-25 |
页码 | 17 |
关键词 | Corrosion inhibitor transition metal complex adsorption acid corrosion |
ISSN号 | 0169-4243 |
DOI | 10.1080/01694243.2021.1929017 |
通讯作者 | Wang, Zhengbin(zbwang12s@imr.ac.cn) |
英文摘要 | The 2,2 '-bipyridine-3,3 '-dicarboxylic acid (bpda) and its transition metal complexes including Ni(bpda)(2), Zn(bpda)(2) and Mn(bpda)(2), were synthesized and tested as corrosion inhibitors for a carbon steel in 0.5 M HCl solution by electrochemical tests and surface analyses. The electrochemical results indicate that the inhibition efficiencies increase with the concentration of corrosion inhibitors. The complexes exhibit higher inhibition efficiencies compared to the bpda ligand, among which Ni(bpda)(2) is the most effective for inhibiting corrosion. The corrosion morphology observation further evidences the superior corrosion inhibition performance of the three complexes. Fourier transform infrared and X-ray photoelectron spectroscopy analyses confirm the spontaneous adsorption of all four inhibitors on the steel surface, and the adsorption analysis suggests a combined physisorption and chemisorption mechanism. Accordingly, the superior corrosion inhibition performance of the three complexes could be attributed to their good adsorption abilities. |
资助项目 | Educational Department of Liaoning Province[LJ2020013] |
WOS研究方向 | Engineering ; Materials Science ; Mechanics |
语种 | 英语 |
WOS记录号 | WOS:000654779700001 |
出版者 | TAYLOR & FRANCIS LTD |
资助机构 | Educational Department of Liaoning Province |
源URL | [http://ir.imr.ac.cn/handle/321006/161055] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Wang, Zhengbin |
作者单位 | 1.Shenyang Univ Chem Technol, Coll Sci, Shenyang, Peoples R China 2.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Xia,Sun, Yue,Lu, Meiheng,et al. Electrochemical and surface analytical studies of transition metal bipyridine dicarboxylic acid complexes as corrosion inhibitors for a mild steel in HCl solution[J]. JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY,2021:17. |
APA | Liu, Xia,Sun, Yue,Lu, Meiheng,Pan, Xuemei,&Wang, Zhengbin.(2021).Electrochemical and surface analytical studies of transition metal bipyridine dicarboxylic acid complexes as corrosion inhibitors for a mild steel in HCl solution.JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY,17. |
MLA | Liu, Xia,et al."Electrochemical and surface analytical studies of transition metal bipyridine dicarboxylic acid complexes as corrosion inhibitors for a mild steel in HCl solution".JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY (2021):17. |
入库方式: OAI收割
来源:金属研究所
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