Catalytically Active Site Identification of Molybdenum Disulfide as Gas Cathode in a Nonaqueous Li-CO2 Battery
文献类型：期刊论文
| 作者 | Chen, Chih-Jung2; Huang, Chih-Sheng2; Huang, Yu-Cheng3; Wang, Fu-Ming4,5,6,7; Wang, Xing-Chun4; Wu, Ching-Chen8; Chang, Wen-Sheng8; Dong, Chung-Li3; Yin, Li-Chang1; Liu, Ru-Shi2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2021-02-10 |
| 卷号 | 13期号:5页码:6156-6167 |
| ISSN号 | 1944-8244 |
| 关键词 | nonaqueous Li-CO2 battery cathode catalyst molybdenum disulfide carbon nanotube sulfided Mo-edge catalytic active sites |
| DOI | 10.1021/acsami.0c17942 |
| 通讯作者 | Dong, Chung-Li(cldong@mail.tku.edu.tw) ; Yin, Li-Chang(lcyin@imr.ac.cn) ; Liu, Ru-Shi(rsliu@ntu.edu.tw) |
| 英文摘要 | Li-CO2 batteries have recently attracted attention as promising candidates for next-generation energy storage devices due to their extremely high theoretical energy density. The real application of Li-CO2 cells involves addressing several drawbacks, including high charging potential, poor coulombic efficiency, and low rechargeability. Molybdenum disulfide supported on carbon nanotubes (MoS2/CNT) with various ratios functioned as a cathode catalyst for Li-CO2 batteries. The optimal MoS2/CNT composite achieved a maximum discharge capacity of 8551 mAh g(-1) with a coulombic efficiency of 96.7%. This hybrid also obtained an initial charging plateau of 3.87 V at a current density of 100 mA g(-1) with a cutoff capacity of 500 mAh g(-1). It provided ideal electrochemical stability of 142 cycles at the current densities of 100 mA g(-1), which was comparable with that of some precious metal catalysts. This optimized MoS2/CNT was also cycled at 200 and 400 mA g(-1) for 112 and 55 times, respectively. Density functional theory calculations demonstrated that the sulfided Mo-edge (s-Mo-edge) on MoS2 materials showed appropriate adsorption strengths of Li, CO2, and Li2CO3. Moreover, joint results of Raman profiles and extended X-ray absorption fine structure spectra elucidated that the catalytic efficiencies of MoS2/CNT hybrids were proportional to the quantities of exposed s-Mo-edge active sites. |
| 资助项目 | Bureau of Energy (BOE), Taiwan ; Ministry of Economy Affairs (MOEA), Taiwan[105-D0114] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000619638400024 |
| 资助机构 | Bureau of Energy (BOE), Taiwan ; Ministry of Economy Affairs (MOEA), Taiwan |
| 源URL | [http://ir.imr.ac.cn/handle/321006/161230]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Dong, Chung-Li; Yin, Li-Chang; Liu, Ru-Shi |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan 3.Tamkang Univ, Dept Phys, Tamsui 25137, Taiwan 4.Natl Taiwan Univ Sci & Technol, Grad Inst Appl Sci & Technol, Taipei 10607, Taiwan 5.Natl Taiwan Univ Sci & Technol, Sustainable Energy Ctr, Taipei 10607, Taiwan 6.Chung Yuan Christian Univ, Dept Chem Engn, Taoyuan 32023, Taiwan 7.Chung Yuan Christian Univ, R&D Ctr Membrane Technol, Taoyuan 32023, Taiwan 8.Ind Technol Res Inst, Green Energy & Environm Res Labs, Hsinchu 31040, Taiwan |
| 推荐引用方式 GB/T 7714 | Chen, Chih-Jung,Huang, Chih-Sheng,Huang, Yu-Cheng,et al. Catalytically Active Site Identification of Molybdenum Disulfide as Gas Cathode in a Nonaqueous Li-CO2 Battery[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(5):6156-6167. |
| APA | Chen, Chih-Jung.,Huang, Chih-Sheng.,Huang, Yu-Cheng.,Wang, Fu-Ming.,Wang, Xing-Chun.,...&Liu, Ru-Shi.(2021).Catalytically Active Site Identification of Molybdenum Disulfide as Gas Cathode in a Nonaqueous Li-CO2 Battery.ACS APPLIED MATERIALS & INTERFACES,13(5),6156-6167. |
| MLA | Chen, Chih-Jung,et al."Catalytically Active Site Identification of Molybdenum Disulfide as Gas Cathode in a Nonaqueous Li-CO2 Battery".ACS APPLIED MATERIALS & INTERFACES 13.5(2021):6156-6167. |
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来源：金属研究所
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