Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes
文献类型：期刊论文
| 作者 | Cao, Tianlong1,2; Dai, Xueya2; Li, Fan2; Liu, Weijie2; Bai, Yunli2; Fu, Yu1; Qi, Wei2 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2021-05-11 |
| 页码 | 8 |
| 关键词 | propane dehydrogenation atomically dispersed cobalt-nitrogen compounds structure-function relationships |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.202100410 |
| 通讯作者 | Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn) |
| 英文摘要 | A hybrid catalyst comprising atomically dispersed cobalt-nitrogen compounds anchoring on oxidized carbon nanotubes (OCNTs) is prepared and applied in propane dehydrogenation (PDH) reactions. The proposed non-precious catalyst exhibits high initial conversion (similar to 20 %) and excellent selectivity of propene (>95 %), which is superior to those of metal-free nanocarbon and some metal-based catalysts. The chemical composition and structure of the proposed hybrid catalysts are elucidated by a series of characterizations and control experiments with a single component. These characterization results combined with the kinetic analysis indicate that the catalytic activity mainly originates from the cobalt-nitrogen (Co-N) species supported on the OCNT surface. The present work sheds light on the structure-function relationships of CoN catalysts, paving the way to develop non-precious catalysts for PDH reactions. |
| 资助项目 | NSFC of China[22072163] ; NSFC of China[21761132010] ; NSFC of China[91645114] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Natural Science Foundation of Liaoning Province of China[2019-MS-296] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000649249100001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NSFC of China ; Natural Science Foundation of Liaoning Province of China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/161617]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Fu, Yu; Qi, Wei |
| 作者单位 | 1.Northeastern Univ, Dept Chem, Coll Sci, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Tianlong,Dai, Xueya,Li, Fan,et al. Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes[J]. CHEMCATCHEM,2021:8. |
| APA | Cao, Tianlong.,Dai, Xueya.,Li, Fan.,Liu, Weijie.,Bai, Yunli.,...&Qi, Wei.(2021).Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes.CHEMCATCHEM,8. |
| MLA | Cao, Tianlong,et al."Efficient Non-Precious Metal Catalyst for Propane Dehydrogenation: Atomically Dispersed Cobalt-nitrogen Compounds on Carbon Nanotubes".CHEMCATCHEM (2021):8. |
入库方式： OAI收割
来源：金属研究所
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