Insight into atmospheric corrosion evolution of mild steel in a simulated coastal atmosphere
文献类型:期刊论文
作者 | Wang, Yue1,2; Mu, Xin1; Dong, Junhua1; Umoh, Aniefiok Joseph1,2; Ke, Wei3 |
刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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出版日期 | 2021-06-20 |
卷号 | 76页码:41-50 |
关键词 | Mild steel Coastal atmospheric corrosion Raman spectroscopy Rusting evolution EIS |
ISSN号 | 1005-0302 |
DOI | 10.1016/j.jmst.2020.11.021 |
通讯作者 | Mu, Xin(xmu@imr.ac.cn) ; Dong, Junhua(jhdong@imr.ac.cn) |
英文摘要 | The corrosion behavior of mild steel in a simulated coastal atmosphere environment has been investigated by the indoor accelerated wet/dry cyclic corrosion acceleration test (CCT), scanning electron microscopy (SEM), Raman spectroscopy and electrochemical measurements. During the CCT test of 60 cycles, the evolution of logarithmic (corrosion rate) vs. logarithmic (CCT cycles) presents a turning point at the 5th cycle, presenting a tendency to increase first and then decrease to gradually stabilize as the CCT cycle prolonged. Before the 5th cycle, gamma-FeOOH and beta-FeOOH and Fe3O4 were detected, respectively. And then, alpha-FeOOH as a new chemical composition was detected in the subsequent corrosion cycles. It is found that, after long term corrosion, the rust separated into a relatively dense inner layer rich with alpha-FeOOH and a loose outer layer rich with gamma-FeOOH, both of which have poor electrical conductivity. The rapid increase of corrosion rate in the early stage since reducible corrosion products are involved in the reduction process of the cathode which promotes the dissolution of the anodic metal substrate. Afterward, as the rust layer thickens, the resistance of the rust increases, and the aggressive ions diffusion is blocked, gradually suppressing the electrochemical corrosion process. At last, when the composition and distribution of the rust layer remain stable, the corrosion presents a fluctuating speed around a certain value during the cracking and self-repairing process of the rust layer. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
资助项目 | Natural ScienceFoundation of Liaoning Province, China[2019JH3/30100037] ; National Natural Science Foundation of China[51671200] ; State Key Laboratory of Metal Material for Marine Equipment and Application[SKLMEA-K201907] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000644511100005 |
出版者 | JOURNAL MATER SCI TECHNOL |
资助机构 | Natural ScienceFoundation of Liaoning Province, China ; National Natural Science Foundation of China ; State Key Laboratory of Metal Material for Marine Equipment and Application |
源URL | [http://ir.imr.ac.cn/handle/321006/161759] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Mu, Xin; Dong, Junhua |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Environm Corros Ctr Mat, Inst Met Res, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Yue,Mu, Xin,Dong, Junhua,et al. Insight into atmospheric corrosion evolution of mild steel in a simulated coastal atmosphere[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,76:41-50. |
APA | Wang, Yue,Mu, Xin,Dong, Junhua,Umoh, Aniefiok Joseph,&Ke, Wei.(2021).Insight into atmospheric corrosion evolution of mild steel in a simulated coastal atmosphere.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,76,41-50. |
MLA | Wang, Yue,et al."Insight into atmospheric corrosion evolution of mild steel in a simulated coastal atmosphere".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 76(2021):41-50. |
入库方式: OAI收割
来源:金属研究所
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