Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives
文献类型：期刊论文
| 作者 | Qi, Fulai2; Sun, Zhenhua2,3; Fan, Xialu2,3; Wang, Zhenxing2,3; Shi, Ying2; Hu, Guangjian2; Li, Feng1,2,3 |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2021-04-15 |
| 页码 | 25 |
| 关键词 | electroactive components interactions lithium‐ sulfur batteries metal‐ organic frameworks |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.202100387 |
| 通讯作者 | Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | Lithium-sulfur (Li-S) batteries, with high theoretical energy density, promise to be the optimal candidate of next-generation energy-storage. Rapid development in materials has made a major step forward in Li-S batteries. However, a big gap in cycle life and efficiency for practical applications still remains. Reasonable design of materials/electrodes a is significant aspect that must be addressed. The rising metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorganic hybrid materials. Abundant inorganic nodes and designable organic linkers allow tailored pore chemistry at a molecular-scale, which enables tunable interaction with electroactive components in Li-S batteries. In this review, the interaction between basic component/structure of MOFs and electroactive components in Li-S batteries is clarified to guide precise function-driven design of MOFs. First, the reaction mechanisms and issues in Li-S batteries are briefly summarized. Second, the structural advantages of MOFs in pore chemistry and morphology are highlighted. Based on the above two aspects of understanding, a bridge between issue-structure-function is proposed. The interaction between MOFs with transport and reaction of electroactive components are discussed. Finally, a perspective on the future development of MOFs based materials in Li-S batteries are given. It is believed that the tunable interaction will boost the frontier interdiscipline of MOFs based electrochemical systems. |
| 资助项目 | National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; National Natural Science Foundation of China[51902316] ; National Natural Science Foundation of China[51525206] ; National Key R&D Program of China[2016YFA0200100] ; National Key R&D Program of China[2016YFB0100100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; LiaoNing Revitalization Talents Program[XLYC1908015] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Special Projects of the Central Government in Guidance of Local Science and Technology Development[2020JH6/10500024] ; China Postdoctoral Science Foundation[2019M651162] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000640240400001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Special Projects of the Central Government in Guidance of Local Science and Technology Development ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.imr.ac.cn/handle/321006/162067]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Sun, Zhenhua; Li, Feng |
| 作者单位 | 1.Shenyang Ind Technol Res Inst Energy Mat & Device, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Fulai,Sun, Zhenhua,Fan, Xialu,et al. Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives[J]. ADVANCED ENERGY MATERIALS,2021:25. |
| APA | Qi, Fulai.,Sun, Zhenhua.,Fan, Xialu.,Wang, Zhenxing.,Shi, Ying.,...&Li, Feng.(2021).Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives.ADVANCED ENERGY MATERIALS,25. |
| MLA | Qi, Fulai,et al."Tunable Interaction between Metal-Organic Frameworks and Electroactive Components in Lithium-Sulfur Batteries: Status and Perspectives".ADVANCED ENERGY MATERIALS (2021):25. |
入库方式： OAI收割
来源：金属研究所
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