Formation mechanism of MC and M2C primary carbides in as-cast M50 bearing steel
文献类型：期刊论文
| 作者 | Du, Ningyu1,2; Liu, Hanghang2; Cao, Yanfei2; Fu, Paixian2; Sun, Chen1,2; Liu, Hongwei2; Li, Dianzhong2 |
| 刊名 | MATERIALS CHARACTERIZATION
 |
| 出版日期 | 2021-04-01 |
| 卷号 | 174页码:14 |
| 关键词 | Bearing steel Primary carbide Segregation Solidification MC M2C |
| ISSN号 | 1044-5803 |
| DOI | 10.1016/j.matchar.2021.111011 |
| 通讯作者 | Liu, Hongwei(hwliu@imr.ac.cn) ; Li, Dianzhong(dzli@imr.ac.cn) |
| 英文摘要 | Based on thermodynamic calculations and experimental characterizations, the characteristics, formation mechanism, and evolution process of two typical primary carbides in as-cast M50 bearing steel were systematically investigated. According to X-ray diffraction (XRD) and transmission electron microscopy (TEM) observations, MC and M2C appear as the V-rich FCC structure and Mo-rich HCP structure, respectively. Thermodynamic calculations show that both carbides cannot precipitate from liquid directly under thermoequilibrium solidification. However, due to the solute-enriched phenomenon during solidification, primary carbides can still form. It is further found that, though both M2C and MC nucleate at these segregated zones, M2C precipitate earlier than MC. It is caused by the distinct segregation extents of Mo and V and undercooling of two primary carbides, which consequently also lead to the difference of growing evolution process and the final carbides morphology. Besides, the Kikuchi patterns obtained by electron backscattered diffraction (EBSD) and the TEM dark-field micrograph show that nucleation position and growth direction of MC and M2C carbides have a selective orientation at the austenite boundaries. Finally, two significant ideas of increasing nucleation by breaking dendrite and adjusting the proportion of Mo and V contents are proposed to control large-sized primary carbides in engineering. |
| 资助项目 | National Key Research and Development Program[2018YFA0702901] ; National Natural Science Foundation of China[51701225] ; National Science and Technology Major Project[2017-VII-0008-0101] ; Young Talent Project by SYNL[L2019F33] ; Innovation project of the cutting-edge basic research and key technology by SYNL[L2019R36] ; Project to Strengthen Industrial Development at the Grass-roots Level[TC190A4DA/35] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000640907100003 |
| 出版者 | ELSEVIER SCIENCE INC |
| 资助机构 | National Key Research and Development Program ; National Natural Science Foundation of China ; National Science and Technology Major Project ; Young Talent Project by SYNL ; Innovation project of the cutting-edge basic research and key technology by SYNL ; Project to Strengthen Industrial Development at the Grass-roots Level |
| 源URL | [http://ir.imr.ac.cn/handle/321006/162120]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Hongwei; Li, Dianzhong |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Ningyu,Liu, Hanghang,Cao, Yanfei,et al. Formation mechanism of MC and M2C primary carbides in as-cast M50 bearing steel[J]. MATERIALS CHARACTERIZATION,2021,174:14. |
| APA | Du, Ningyu.,Liu, Hanghang.,Cao, Yanfei.,Fu, Paixian.,Sun, Chen.,...&Li, Dianzhong.(2021).Formation mechanism of MC and M2C primary carbides in as-cast M50 bearing steel.MATERIALS CHARACTERIZATION,174,14. |
| MLA | Du, Ningyu,et al."Formation mechanism of MC and M2C primary carbides in as-cast M50 bearing steel".MATERIALS CHARACTERIZATION 174(2021):14. |
入库方式： OAI收割
来源：金属研究所
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