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Chinese Academy of Sciences Institutional Repositories Grid
A hidden precipitation scenario of the theta'-phase in Al-Cu alloys

文献类型:期刊论文

作者Zhou, L.1; Wu, C. L.1; Xie, P.1; Niu, F. J.1; Ming, W. Q.1; Du, K.2; Chen, J. H.1
刊名JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
出版日期2021-06-10
卷号75页码:126-138
关键词AlCu alloy Age-hardening Precipitation Electron microscopy
ISSN号1005-0302
DOI10.1016/j.jmst.2020.09.039
通讯作者Wu, C. L.(cuilanwu@hnu.edu.cn) ; Chen, J. H.(jhchen123@hnu.edu.cn)
英文摘要Al-Cu binary alloys are important and interesting industry materials. Up to date, the formation mechanisms of the key strengthening precipitates, named theta'-phase, in the alloys are still controversial. Here, we report that for non-deformed bulk Al-Cu alloys the theta'-phase actually has its own direct precursors that can form only at elevated aging temperature (> ca. 200 degrees C). These high-temperature precursors have the same plate-like morphology as the theta'-phase precipitates but rather different structures. Atomic-resolution imaging reveals that they have a tetragonal structure with a = 0.405 nm and c = 1.213 nm, and an average composition of Al5-xCu1+ x (0 <= x <1), being fully coherent with the Al-lattice. This precursor phase may initiate with a composition of Al5Cu and evolve locally towards Al4Cu2 in composition, eventually leading to a consequent structural transformation into the theta'-phase (Al4Cu2=Al2Cu). There are evidences that because of their genetic links in structure, such a high-temperature precursor may transform to the theta'-phase without having to change their morphology and interface structure. Our study reveals a well-defined and previously hidden precipitation scenario for the theta'-phase to form in Al-Cu alloys at an elevated aging temperature. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
资助项目National Natural Science Foundation of China[51831004] ; National Natural Science Foundation of China[51801060] ; National Natural Science Foundation of China[51671082] ; National Natural Science Foundation of China[11427806] ; National Natural Science Foundation of China[51471067] ; National Key Research and Development Program of China[2016YFB0300801]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000640021600014
出版者JOURNAL MATER SCI TECHNOL
资助机构National Natural Science Foundation of China ; National Key Research and Development Program of China
源URL[http://ir.imr.ac.cn/handle/321006/162223]  
专题金属研究所_中国科学院金属研究所
通讯作者Wu, C. L.; Chen, J. H.
作者单位1.Hunan Univ, Coll Mat Sci & Engn, Ctr High Resolut Electron Microscopy, Changsha 410082, Hunan, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Zhou, L.,Wu, C. L.,Xie, P.,et al. A hidden precipitation scenario of the theta'-phase in Al-Cu alloys[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,75:126-138.
APA Zhou, L..,Wu, C. L..,Xie, P..,Niu, F. J..,Ming, W. Q..,...&Chen, J. H..(2021).A hidden precipitation scenario of the theta'-phase in Al-Cu alloys.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,75,126-138.
MLA Zhou, L.,et al."A hidden precipitation scenario of the theta'-phase in Al-Cu alloys".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 75(2021):126-138.

入库方式: OAI收割

来源:金属研究所

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