Thermodynamic properties and prediction of viscosity for ternary solution (VOSO4 + PAA+ H2O) in vanadium flow battery
文献类型：期刊论文
| 作者 | Guo, Yushi1; Wu, Ling3; Jiang, Chenglin2; Zhao, Jinling2; Feng, Lutian1; Zhang, Kaiyue2; Qin, Ye1; Li, Xiangrong2; Liu, Jianguo2; Yan, Chuanwei2 |
| 刊名 | JOURNAL OF MOLECULAR LIQUIDS
 |
| 出版日期 | 2021-04-15 |
| 卷号 | 328页码:6 |
| 关键词 | Vanadium redox flow battery Polyacrylic acid Viscosity Eyring's theory Prediction equation for viscosity |
| ISSN号 | 0167-7322 |
| DOI | 10.1016/j.molliq.2021.115510 |
| 通讯作者 | Qin, Ye(qinye@syuct.edu.cn) ; Li, Xiangrong(xrli@imr.ac.cn) ; Liu, Jianguo(jgliu@imr.ac.cn) |
| 英文摘要 | A number of additives have been proven to improve the performance of vanadiumredox flow batteries (VRFBs). Polyacrylic acid (PAA) is considered to be one of the promising candidates because of its beneficial effects on the stability of batteries. This paper studied the influence of PAA on viscosity, which is one of the electrolyte transport properties. The viscosity of VOSO4 + PAA + H2O ternary solution was measured at different temperature, ionic strength, and ionic strength fractions in the temperature range of 283.15 K-318.15 K. Several thermodynamic parameters of the PAA aqueous solution were calculated, such as the viscosity B-coefficients, the apparent molar volume of infinite dilution and the free energy of activation. In addition, two different semi-empirical prediction equations were established for ternary solution viscosity on the basis of the Eyring's theory, and the better one was determined through comparison. The average relative deviation is 0.74% between the predicted and the experimental values, which indicates this function can be used to predict the viscosity of VOSO4 + PAA + H2O ternary solution. (C) 2021 Elsevier B.V. All rights reserved. |
| 资助项目 | National Natural Science Foundation of China[51973124] ; National Natural Science Foundation of China[21805290] ; Educational Department of Liaoning Province, China[LQ2017007] ; Educational Department of Liaoning Province, China[LQ2019012] ; Department of Science & Technology of Liaoning Province, China[2019JH3/30100012] ; Department of Human Resources and Social Security of Liaoning Province, China[[2020] 78] |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000637338200111 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Educational Department of Liaoning Province, China ; Department of Science & Technology of Liaoning Province, China ; Department of Human Resources and Social Security of Liaoning Province, China |
| 源URL | [http://ir.imr.ac.cn/handle/321006/162249]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Qin, Ye; Li, Xiangrong; Liu, Jianguo |
| 作者单位 | 1.Shenyang Univ Chem Technol, Shenyang 110142, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Liaoning Univ, Shenyang 110136, Peoples R China 4.Liaoning Tobacco Co, Shenyang 110062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Yushi,Wu, Ling,Jiang, Chenglin,et al. Thermodynamic properties and prediction of viscosity for ternary solution (VOSO4 + PAA+ H2O) in vanadium flow battery[J]. JOURNAL OF MOLECULAR LIQUIDS,2021,328:6. |
| APA | Guo, Yushi.,Wu, Ling.,Jiang, Chenglin.,Zhao, Jinling.,Feng, Lutian.,...&Lei, Ming.(2021).Thermodynamic properties and prediction of viscosity for ternary solution (VOSO4 + PAA+ H2O) in vanadium flow battery.JOURNAL OF MOLECULAR LIQUIDS,328,6. |
| MLA | Guo, Yushi,et al."Thermodynamic properties and prediction of viscosity for ternary solution (VOSO4 + PAA+ H2O) in vanadium flow battery".JOURNAL OF MOLECULAR LIQUIDS 328(2021):6. |
入库方式： OAI收割
来源：金属研究所
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