In situ immobilization of Fe/Fe3C/Fe2O3 hollow hetero-nanoparticles onto nitrogen-doped carbon nanotubes towards high-efficiency electrocatalytic oxygen reduction
文献类型：期刊论文
| 作者 | Zhang, Binbin1; Li, Tongfei1; Huang, Longzhen1; Ren, Yiping1; Sun, Dongmei1; Pang, Huan2; Yang, Jun3,4; Xu, Lin1; Tang, Yawen1 |
| 刊名 | NANOSCALE
 |
| 出版日期 | 2021-03-14 |
| 卷号 | 13期号:10页码:5400-5409 |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/d1nr00078k |
| 英文摘要 | The rational design of affordable, efficient and robust electrocatalysts towards the oxygen reduction reaction (ORR) is of vital importance for the future advancement of various renewable-energy technologies. Herein, we develop a feasible and delicate synthesis of Fe/Fe3C/Fe2O3 hollow heterostructured nanoparticles in situ immobilized on highly graphitic nitrogen-doped carbon nanotubes (referred to as Fe/Fe3C/Fe2O3@N-CNTs hereafter) via a simple hydrogel-bridged pyrolysis strategy. The simultaneous consideration of interfacial manipulation and nanocarbon hybridization endows the formed Fe/Fe3C/Fe2O3@N-CNTs with sufficiently well-dispersed and firmly immobilized active components, regulated electronic configuration, enhanced electrical conductivity, multidimensional mass transport channels, and remarkable structural stability. Consequently, benefiting from the compositional synergy and architectural superiority, the as-obtained Fe/Fe3C/Fe2O3@N-CNTs exhibit excellent ORR catalytic activity, impressive durability and superior selectivity in an alkaline electrolyte, outperforming the commercial Pt/C catalyst and a majority of the previously reported Fe-based catalysts. Furthermore, the rechargeable Zn-air battery using Fe/Fe3C/Fe2O3@N-CNTs + RuO2 as an air-cathode exhibits a higher power density, larger specific capacity and better cycling stability as compared with the state-of-the-art Pt/C + RuO2 counterpart. The explored hydrogel-bridged pyrolysis strategy enabling the concurrent heterointerface construction, nanostructure engineering and nanocarbon hybridization may inspire the future design of high-efficiency electrocatalysts for diverse renewable energy applications. |
| 资助项目 | National Natural Science Foundation of China[21972068] ; National Natural Science Foundation of China[21875112] ; National Natural Science Foundation of China[22075290] ; Qing Lan Project of Jiangsu Province ; Nanjing IPE Institute of Green Manufacturing Industry ; Beijing Natural Science Foundation[Z200012] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000630384400022 |
| 资助机构 | National Natural Science Foundation of China ; Qing Lan Project of Jiangsu Province ; Nanjing IPE Institute of Green Manufacturing Industry ; Beijing Natural Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/47988]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xu, Lin; Tang, Yawen |
| 作者单位 | 1.Nanjing Normal Univ, Sch Chem & MateriaLc Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China 2.Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225009, Peoples R China 3.Nanjing IPE Inst Green Mfg Ind, Nanjing 211100, Peoples R China 4.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Binbin,Li, Tongfei,Huang, Longzhen,et al. In situ immobilization of Fe/Fe3C/Fe2O3 hollow hetero-nanoparticles onto nitrogen-doped carbon nanotubes towards high-efficiency electrocatalytic oxygen reduction[J]. NANOSCALE,2021,13(10):5400-5409. |
| APA | Zhang, Binbin.,Li, Tongfei.,Huang, Longzhen.,Ren, Yiping.,Sun, Dongmei.,...&Tang, Yawen.(2021).In situ immobilization of Fe/Fe3C/Fe2O3 hollow hetero-nanoparticles onto nitrogen-doped carbon nanotubes towards high-efficiency electrocatalytic oxygen reduction.NANOSCALE,13(10),5400-5409. |
| MLA | Zhang, Binbin,et al."In situ immobilization of Fe/Fe3C/Fe2O3 hollow hetero-nanoparticles onto nitrogen-doped carbon nanotubes towards high-efficiency electrocatalytic oxygen reduction".NANOSCALE 13.10(2021):5400-5409. |
入库方式： OAI收割
来源：过程工程研究所
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