A stepwise separation process for selective recovery of gallium from hydrochloric acid leach liquor of coal fly ash
文献类型：期刊论文
| 作者 | Zhao, Zesen2; Cui, Li2; Guo, Yanxia2; Gao, Jianming2; Li, Huiquan1; Cheng, Fangqin2 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2021-06-15 |
| 卷号 | 265页码:9 |
| 关键词 | Coal fly ash Gallium Polyurethane foam Hydrochloric acid |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2021.118455 |
| 英文摘要 | The interest in gallium (Ga) recovery from coal fly ash has been driven by its rapidly growing demand for manufacturing and its extraction can facilitate the effective use of coal fly ash, which is conducive to reducing the soil degradation and environment danger. In this study, polyurethane foam (PUF) as an adsorbent for Ga(III) recovery was found to exhibit a good structural stability and a high selectivity in a strongly acidic solution. Adsorption measurements show that PUF has a good adsorption ability and its maximum adsorption capacity is 62.53 mg/g. Furthermore, its adsorption behavior can be described well by the pseudo-second-order model. The concentrations of Cl(I) played the key role in the adsorption. Meanwhile, the co-existed Fe(III) in the coal fly ash hydrochloric acid leach liquor (CFAHL) exhibits significant interference to the selective adsorption of Ga(III). Therefore, a stepwise process involving Fe(III) removal and Ga(III) adsorption is proposed for the recovery Ga from CFAHL. At an equilibrium pH of 0, the Fe(III) in the CFAHL can be removed by 1 mol/L P507. Then, the Ga (III) can be quantitatively adsorbed from the CFAHL using PUF with limited co-adsorption of Al(III), Mg(II), and Ca(II). The adsorption capacity of Ga(III) remains steady after PUF is used for more than 10 cycles. Based on the results of IR, XPS and DFT, it is speculated that the Ga(III) is probably coordinated in the form of GaCl3 with the donor O atoms of the urethane group (?NHCOO?) on the PUF surface. The overall results demonstrate the potential use of PUF for Ga recovery from acidic solutions. |
| 资助项目 | National Natural Science Foundation of China[U1810205] ; National Key R&D Program of China[2017YFB0603101] ; Shanxi Province Coal Based Lowcarbon Technology Major Projects[MC2016-05] ; Xiangyuan Key Technology Research Projects[2018XYSDYY02] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000634729300005 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China ; Shanxi Province Coal Based Lowcarbon Technology Major Projects ; Xiangyuan Key Technology Research Projects |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/48103]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Guo, Yanxia; Cheng, Fangqin |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing, Peoples R China 2.Shanxi Univ, Inst Resources & Environm Engn, State Environm Protect Key Lab Efficient Utilizat, Taiyuan 030006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Zesen,Cui, Li,Guo, Yanxia,et al. A stepwise separation process for selective recovery of gallium from hydrochloric acid leach liquor of coal fly ash[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2021,265:9. |
| APA | Zhao, Zesen,Cui, Li,Guo, Yanxia,Gao, Jianming,Li, Huiquan,&Cheng, Fangqin.(2021).A stepwise separation process for selective recovery of gallium from hydrochloric acid leach liquor of coal fly ash.SEPARATION AND PURIFICATION TECHNOLOGY,265,9. |
| MLA | Zhao, Zesen,et al."A stepwise separation process for selective recovery of gallium from hydrochloric acid leach liquor of coal fly ash".SEPARATION AND PURIFICATION TECHNOLOGY 265(2021):9. |
入库方式： OAI收割
来源：过程工程研究所
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