Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2
文献类型：期刊论文
| 作者 | Xia, Shi-Ping2,3; Ding, Guang-Rong1,3; Zhang, Rui2; Han, Li-Jun3; Xu, Bao-Hua1,3; Zhang, Suo-Jiang1,3 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2021-03-26 |
| 页码 | 8 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/d0gc04386a |
| 英文摘要 | In this study, the heterogeneously catalyzed alkoxycarbonylation of olefins with CO2 based on a supported ionic-liquid-phase (SILP) strategy is reported for the first time. An [Ru]@SILP catalyst was accessed by immobilization of ruthenium complex on a SILP, wherein imidazolium chloride was chemically integrated at the surface or in the channels of the silica gel support. An active Ru site was generated through reacting Ru-3(CO)(12) with the decorated imidazolium chloride in a proper microenvironment. Different IL films, by varying the functionality of the side chain at the imidazolium cation, were found to strongly affect the porosity, active Ru sites, and CO2 adsorption capacity of [Ru]@SILP, thereby considerably influencing its catalytic performance. The optimized [Ru]@SILP-A-2 displayed enhanced catalytic performance and prominent substrate selectivity compared to an independent homogeneous system under identical conditions. These findings provide the basis for a novel design concept for achieving both efficient and stable catalysts in the coupling of CO2 with olefins. |
| 资助项目 | Excellent Young Scientists Fund[22022815] ; Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; National Natural Science Foundation of China[U1704251] ; National Natural Science Foundation of China[22078336] ; National Natural Science Foundation of China[21374029] ; Zhengzhou High Level Talent Certificate[20180200052] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000639548100001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Excellent Young Scientists Fund ; Key Research Program of Frontier Sciences, CAS ; National Natural Science Foundation of China ; Zhengzhou High Level Talent Certificate |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/48244]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Rui; Xu, Bao-Hua |
| 作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 2.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Shi-Ping,Ding, Guang-Rong,Zhang, Rui,et al. Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2[J]. GREEN CHEMISTRY,2021:8. |
| APA | Xia, Shi-Ping,Ding, Guang-Rong,Zhang, Rui,Han, Li-Jun,Xu, Bao-Hua,&Zhang, Suo-Jiang.(2021).Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2.GREEN CHEMISTRY,8. |
| MLA | Xia, Shi-Ping,et al."Ruthenium complex immobilized on supported ionic-liquid-phase (SILP) for alkoxycarbonylation of olefins with CO2".GREEN CHEMISTRY (2021):8. |
入库方式： OAI收割
来源：过程工程研究所
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