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Super selective ammonia separation through multiple-site interaction with ionic liquid-based hybrid membranes

文献类型：期刊论文

作者Yang, Bingbing1,4; Bai, Lu4; Li, Tingting4,5; Deng, Liyuan2; Liu, Lei4; Zeng, Shaojuan4; Han, Jiuli1,4; Zhang, Xiangping1,3,4
刊名JOURNAL OF MEMBRANE SCIENCE
出版日期2021-06-15
卷号628页码:10
关键词Ionic liquids Hybrid membranes Ammonia separation Nexar Ionic domains
ISSN号0376-7388
DOI10.1016/j.memsci.2021.119264
英文摘要Efficient separation and recovery of ammonia (NH3) is essential for environmental protection and resource utilization. In this work, hybrid membranes for NH3 separation through multiple-site interaction were developed by combining the unique features of ionic liquids (ILs) and a midblock-sulfonated block copolymer. The functionalized ILs ([2-Mim][NTf2] and [Im][NTf2]) with ammonia interaction sites were incorporated into the NexarTM matrix, which greatly improves the affinity for NH3 over nitrogen (N2) and hydrogen (H2). Benefited from the self-assembly of the block copolymer, the hybrid membranes primarily exhibit lamellar morphology. More continuous ionic domains with well-distributed ILs were formed in the hybrid membranes, contributing to forming interconnected channels for enhanced gas transport. In this case, addition of the ILs into the Nexar matrix significantly enhances NH3 separation performance. Nexar/[Im][NTf2]-25 membrane achieves the highest NH3 permeability of 3565 Barrer and a maximum NH3/N2 and NH3/H2 ideal selectivity of 1865 and 364, respectively. The significantly enhanced NH3 permeation compared with the neat Nexar membrane indicates the positive role of ILs in the hybrid membranes.
资助项目National Natural Science Foundation of China[21978306] ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China[21921005] ; International (Regional) Cooperation and Exchange of the National Natural Science Foundation of China[21961160744] ; International Partnership Program of Chinese Academy of Sciences[122111KYSB20190029]
WOS研究方向Engineering ; Polymer Science
语种英语
WOS记录号WOS:000640906600001
出版者ELSEVIER
资助机构National Natural Science Foundation of China ; Science Fund for Creative Research Groups of the National Natural Science Foundation of China ; International (Regional) Cooperation and Exchange of the National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences
源URL[http://ir.ipe.ac.cn/handle/122111/48535]  
专题中国科学院过程工程研究所
通讯作者Bai, Lu; Zhang, Xiangping
作者单位1.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
2.Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway
3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China
4.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China
5.Zhengzhou Univ, Coll Chem Engn, Zhengzhou 450001, Peoples R China
推荐引用方式
GB/T 7714		 Yang, Bingbing,Bai, Lu,Li, Tingting,et al. Super selective ammonia separation through multiple-site interaction with ionic liquid-based hybrid membranes[J]. JOURNAL OF MEMBRANE SCIENCE,2021,628:10.
APA Yang, Bingbing.,Bai, Lu.,Li, Tingting.,Deng, Liyuan.,Liu, Lei.,...&Zhang, Xiangping.(2021).Super selective ammonia separation through multiple-site interaction with ionic liquid-based hybrid membranes.JOURNAL OF MEMBRANE SCIENCE,628,10.
MLA Yang, Bingbing,et al."Super selective ammonia separation through multiple-site interaction with ionic liquid-based hybrid membranes".JOURNAL OF MEMBRANE SCIENCE 628(2021):10.

入库方式： OAI收割

来源：过程工程研究所

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