Characteristics of lignite char derived from oxy-pyrolysis
文献类型：期刊论文
| 作者 | Qi, Jianan1,2,3; Fan, Cuigang1,3; Li, Songgeng1,3,4 |
| 刊名 | FUEL
 |
| 出版日期 | 2021-05-01 |
| 卷号 | 291页码:9 |
| 关键词 | Oxy-pyrolysis Lignite char Structure evolution Reactivity |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2021.120261 |
| 英文摘要 | Lignite chars were prepared in a fixed bed reactor under various oxygen concentrations (0-15 vol%) and pyrolysis temperatures (873 K-1173 K). Characterization techniques such as Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and BET were applied to reveal the impacts of temperature and oxygen concentration on char structure evolution during pyrolysis. Combustion performances of the prepared chars were examined on a thermal gravimetric analyzer, using ignition and burnout temperatures as indexes of char reactivity. On a whole, oxy-pyrolysis char is more reactive than the char derived under inert (N2) atmosphere. Raman analysis indicates that the presence of oxygen during pyrolysis can reduce the extent of char graphitization at high temperatures and favors the removal of oxygen containing groups and aliphatic structures. Pore volume and specific surface area can be improved due to the presence of oxygen in pyrolysis. There is a critical oxygen concentration at high pyrolysis temperatures. Releasing behaviors of sulfur and nitrogen, and their speciation and distributions on the prepared chars were also discussed. |
| WOS关键词 | LOW-TEMPERATURE PYROLYSIS ; COAL CHAR ; CATALYTIC CRACKING ; REACTION-MECHANISM ; HEAT-TREATMENT ; EVOLUTION ; SULFUR ; GASIFICATION ; OXIDATION ; NITROGEN |
| 资助项目 | "Strategic Priority Research Program" of the Chinese Academy of Sciences[XDA21040400] ; National Natural Science Foundation of China[21978305] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000651782800007 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | "Strategic Priority Research Program" of the Chinese Academy of Sciences ; National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/48708]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Songgeng |
| 作者单位 | 1.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China 2.Sino Danish Ctr Educ & Res, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Jianan,Fan, Cuigang,Li, Songgeng. Characteristics of lignite char derived from oxy-pyrolysis[J]. FUEL,2021,291:9. |
| APA | Qi, Jianan,Fan, Cuigang,&Li, Songgeng.(2021).Characteristics of lignite char derived from oxy-pyrolysis.FUEL,291,9. |
| MLA | Qi, Jianan,et al."Characteristics of lignite char derived from oxy-pyrolysis".FUEL 291(2021):9. |
入库方式： OAI收割
来源：过程工程研究所
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