Synthesis of alkyl polyglycosides using SO3H-functionalized ionic liquids as catalysts
文献类型：期刊论文
| 作者 | Wu, Wenliang1,2; Gao, Hongshuai1,2; Hai, Bin1; Wang, Binqi1; Yu, Min1; Nie, Yi1,2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2021-05-01 |
| 卷号 | 11期号:24页码:14710-14716 |
| DOI | 10.1039/d1ra00337b |
| 英文摘要 | An effective process for synthesis of alkyl polyglycosides (APG) was developed using SO3H-functionalized ionic liquids (SFILs) as catalysts. Four SFILs, [PSmim][HSO4], [PSmim][pTSA], [PSPy][HSO4] and [PSPy][pTSA], were designed and synthesized for APG synthesis. The results indicated that [PSmim][HSO4] shows the best catalytic performance among these four SFILs, which has a great agreement with the order of their acidities. When the [PSmim][HSO4] was used as catalyst, the reaction time could be decreased from 24 h to 8 h, and molar ration of n-octanol to glucose could be decreased from 5 : 1 to 3 : 1 under the optimization reaction conditions. In addition, the [PSmim][HSO4] could be easily regenerated and recycled at least 5 times with slight decrease in catalytic activity. Moreover, the catalytic mechanism of [PSmim][HSO4] was further investigated by molecular simulation. The high catalytic activity of [PSmim][HSO4] is attributed to hydrogen bonds between [PSmim][HSO4] and glucose and n-octanol, which could accelerate the protonation of glucose and removal of hydrogen ions from the hydroxyl in n-octanol. |
| WOS关键词 | REUSABLE CATALYST ; HYDROGEN-BOND ; CONVERSION ; EFFICIENT ; ACIDITY ; SYSTEM |
| 资助项目 | National Natural Science Foundation of China[22078323] ; National Natural Science Foundation of China[51574215] ; National Natural Science Foundation of China[21436010] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000648696300048 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/48847]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Gao, Hongshuai; Nie, Yi |
| 作者单位 | 1.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450046, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Wenliang,Gao, Hongshuai,Hai, Bin,et al. Synthesis of alkyl polyglycosides using SO3H-functionalized ionic liquids as catalysts[J]. RSC ADVANCES,2021,11(24):14710-14716. |
| APA | Wu, Wenliang,Gao, Hongshuai,Hai, Bin,Wang, Binqi,Yu, Min,&Nie, Yi.(2021).Synthesis of alkyl polyglycosides using SO3H-functionalized ionic liquids as catalysts.RSC ADVANCES,11(24),14710-14716. |
| MLA | Wu, Wenliang,et al."Synthesis of alkyl polyglycosides using SO3H-functionalized ionic liquids as catalysts".RSC ADVANCES 11.24(2021):14710-14716. |
入库方式： OAI收割
来源：过程工程研究所
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