Pt/TS-1 catalysts: Effect of the platinum loading method on the dehydrogenation of n-butane
文献类型：期刊论文
| 作者 | Shao, Mingyuan1,2,3; Hu, Chaoquan1,2,3; Xu, Xuebing1,2; Song, Yang1; Zhu, Qingshan1,2,3 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2021-07-05 |
| 卷号 | 621页码:9 |
| 关键词 | N-butane Direct dehydrogenation Pre-reduction DFT Particle size |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2021.118194 |
| 英文摘要 | A series of catalysts in which platinum was supported on the crystalline pure titanium silicalite (TS-1) were prepared using two different loading methods, namely, an ethylene glycol (EG) reduction method and the conventional incipient wetness impregnation (IM) technique. Various characterization techniques were used to study the effect of the loading method on the physicochemical and morphological properties of the prepared catalysts. Also the effect of the platinum-loading method on the dehydrogenation of n-butane was investigated in a fixed-bed reactor. The results show that the EG method favors the formation of a more-concentrated Pt dispersion, which results in much better catalytic activities for the selective formation of butenes and butadiene (> 97 %). This phenomenon is interpreted by carrying out density functional theory (DFT) calculations with focus on the relationship between the coverage of n-butane on Pt surface and the activation barrier for the first C-H bond cleavage. |
| WOS关键词 | IN-SITU DRIFT ; OXIDATIVE DEHYDROGENATION ; PROPANE DEHYDROGENATION ; ALLOY ; CO ; PERFORMANCE ; ADSORPTION ; CE |
| 资助项目 | National Natural Science Foundation of China[22078328] |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000656678600004 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/48978]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Hu, Chaoquan; Zhu, Qingshan |
| 作者单位 | 1.Nanjing IPE Inst Green Mfg Ind, Nanjing, Peoples R China 2.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Inst Proc Engn, Beijing, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Mingyuan,Hu, Chaoquan,Xu, Xuebing,et al. Pt/TS-1 catalysts: Effect of the platinum loading method on the dehydrogenation of n-butane[J]. APPLIED CATALYSIS A-GENERAL,2021,621:9. |
| APA | Shao, Mingyuan,Hu, Chaoquan,Xu, Xuebing,Song, Yang,&Zhu, Qingshan.(2021).Pt/TS-1 catalysts: Effect of the platinum loading method on the dehydrogenation of n-butane.APPLIED CATALYSIS A-GENERAL,621,9. |
| MLA | Shao, Mingyuan,et al."Pt/TS-1 catalysts: Effect of the platinum loading method on the dehydrogenation of n-butane".APPLIED CATALYSIS A-GENERAL 621(2021):9. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。