Ru(bpy)(3)(2+)-sensitized {001} facets LiCoO2 nanosheets catalyzed CO2 reduction reaction with 100% carbonaceous products
文献类型：期刊论文
| 作者 | Jiang, Shuaiyu5; Liu, Junxian5; Zhao, Kun5; Cui, Dandan3,4; Liu, Porun5; Yin, Huajie5; Al-Mamun, Mohammad5; Lowe, Sean E.5; Zhang, Weiping2; Zhong, Yu Lin5 |
| 刊名 | NANO RESEARCH
 |
| 出版日期 | 2021-07-10 |
| 页码 | 8 |
| ISSN号 | 1998-0124 |
| 关键词 | homogeneous-heterogeneous catalysis system ultrathin LiCoO2 nanosheets photocatalytic CO2 reduction suppressed hydrogen evolution reaction |
| DOI | 10.1007/s12274-021-3599-1 |
| 英文摘要 | Photosensitized heterogeneous CO2 reduction (PHCR) has emerged as a promising means to convert CO2 into valuable chemicals, however, challenged by the relatively low carbonaceous product selectivity caused by the competing hydrogen evolution reaction (HER). Here, we report a PHCR system that couples Ru(bpy)(3)(2+) photosensitizer with {001} faceted LiCoO2 nanosheets photocatalyst to simultaneously yield 21.2 and 722 mu mol.g(-1).h(-1) of CO, and 4.42 and 108 mu mol.g(-1).h(-1) of CH4 under the visible light and the simulated sunlight irradiations, respectively, with completely suppressed HER. The experimental and theoretical studies reveal that the favored CO2 adsorption on the exposed Li sites on {001} faceted LiCoO2 surface is responsible for the completely suppressed HER. |
| WOS关键词 | PHOTOCATALYTIC REDUCTION ; PHOTOREDUCTION ; COCATALYST ; DIOXIDE ; WATER |
| 资助项目 | Australian Research Council[DP170104834] ; Australian Research Council[DP200100965] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | TSINGHUA UNIV PRESS |
| WOS记录号 | WOS:000671638500002 |
| 资助机构 | Australian Research Council |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49500]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhao, Kun; Liu, Porun; Zhao, Huijun |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China 2.Guangdong Univ Technol, Sch Environm Sci & Engn, Guangdong Key Lab Environm Catalysis & Hlth Risk, Inst Environm Hlth & Pollut Control,Guangzhou Key, Guangzhou 510006, Peoples R China 3.Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2500, Australia 4.Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2500, Australia 5.Griffith Univ, Ctr Catalysis & Clean Energy, Gold Coast Campus, Gold Coast, Qld 4222, Australia |
| 推荐引用方式 GB/T 7714 | Jiang, Shuaiyu,Liu, Junxian,Zhao, Kun,et al. Ru(bpy)(3)(2+)-sensitized {001} facets LiCoO2 nanosheets catalyzed CO2 reduction reaction with 100% carbonaceous products[J]. NANO RESEARCH,2021:8. |
| APA | Jiang, Shuaiyu.,Liu, Junxian.,Zhao, Kun.,Cui, Dandan.,Liu, Porun.,...&Zhao, Huijun.(2021).Ru(bpy)(3)(2+)-sensitized {001} facets LiCoO2 nanosheets catalyzed CO2 reduction reaction with 100% carbonaceous products.NANO RESEARCH,8. |
| MLA | Jiang, Shuaiyu,et al."Ru(bpy)(3)(2+)-sensitized {001} facets LiCoO2 nanosheets catalyzed CO2 reduction reaction with 100% carbonaceous products".NANO RESEARCH (2021):8. |
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来源：过程工程研究所
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