Highly Dispersed Cu/Graphene Nanocatalyst Guided by MOF Structure: Application to Methanol Synthesis from CO2 Hydrogenation
文献类型：期刊论文
| 作者 | San, Xiaoguang4; Gong, Xiaohui4; Hu, Yanbing3; Hu, Yue2; Wang, Guosheng4; Qi, Jian1; Meng, Dan4; Jin, Quan2 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2021-06-28 |
| 卷号 | 6期号:24页码:6115-6118 |
| 关键词 | CO2 hydrogenation graphene methanol synthesis MOFs |
| ISSN号 | 2365-6549 |
| DOI | 10.1002/slct.202101179 |
| 英文摘要 | The dispersion of heterogeneous catalyst is directly related to the performance. In this work, highly dispersed Cu/graphene catalyst was successfully prepared by adopting a "template genetic inheritance" (TGI). The metal-organic frameworks (MOFs) were introduced between the graphene sheets. Due to the spatial structure of MOFs, the Cu atoms arranged in the expected direction after removing the MOFs skeleton, which lead to a highly orderly dispersion of the Cu particles with uniform sized. Meanwhile, graphene provided a large specific surface area and a carbon source for in-situ reduction of CuO. Furthermore, the CO2 hydrogenation to methanol performance was analyzed and more than 22 % conversion of CO2 and 84 % selectivity of methanol was achieved. This work provides a simple and novel strategy for the preparation of highly dispersed metal particle supported catalysts, which may be used in catalysis and other fields. |
| WOS关键词 | CARBON-DIOXIDE ; CATALYST |
| 资助项目 | National Natural Science Foundation of China[61973223] ; National Natural Science Foundation of China[51672276] ; National Natural Science Foundation of China[51772294] ; National Natural Science Foundation of China[51972306] ; Liaoning Educational Department Foundation[LQ2019013] ; Liaoning Provincial Natural Science Foundation[2019-ZD-0072] ; Liaoning Revitalization Talents Program[XLYC2007051] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000674320500035 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Liaoning Educational Department Foundation ; Liaoning Provincial Natural Science Foundation ; Liaoning Revitalization Talents Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49539]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Meng, Dan; Jin, Quan |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 2.Jilin Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Automobile Mat, 5988 Renmin St, Changchun 130022, Peoples R China 3.Jilin Univ, Hosp 2, 218 Zigiang St, Changchun 130021, Peoples R China 4.Shenyang Univ Chem Technol, Coll Chem Engn, 11th St, Shenyang 110142, Peoples R China |
| 推荐引用方式 GB/T 7714 | San, Xiaoguang,Gong, Xiaohui,Hu, Yanbing,et al. Highly Dispersed Cu/Graphene Nanocatalyst Guided by MOF Structure: Application to Methanol Synthesis from CO2 Hydrogenation[J]. CHEMISTRYSELECT,2021,6(24):6115-6118. |
| APA | San, Xiaoguang.,Gong, Xiaohui.,Hu, Yanbing.,Hu, Yue.,Wang, Guosheng.,...&Jin, Quan.(2021).Highly Dispersed Cu/Graphene Nanocatalyst Guided by MOF Structure: Application to Methanol Synthesis from CO2 Hydrogenation.CHEMISTRYSELECT,6(24),6115-6118. |
| MLA | San, Xiaoguang,et al."Highly Dispersed Cu/Graphene Nanocatalyst Guided by MOF Structure: Application to Methanol Synthesis from CO2 Hydrogenation".CHEMISTRYSELECT 6.24(2021):6115-6118. |
入库方式： OAI收割
来源：过程工程研究所
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