Development of a highly stable Pt-based ORR catalyst over Mn-modified polyaniline-based carbon nanofibers
文献类型：期刊论文
| 作者 | Yu, Jinghua4; Zhou, Qian4; Xue, Xiaoyi3; Zhang, Haitao2; Li, Xiaojin1; Wang, Fanghui4; Chen, Qingjun1,2,3; Zhu, Hong4 |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2021-06-15 |
| 页码 | 8 |
| ISSN号 | 1144-0546 |
| DOI | 10.1039/d1nj01304a |
| 英文摘要 | The corrosion of carbon support is one of the key factors causing the deactivation of Pt-based oxygen reduction reaction (ORR) catalysts for proton exchange membrane fuel cells. In this work, a highly stable carbon support with a high graphitization degree, small diameter, and large surface area (polyaniline-based carbon nanofibers, CNF-1300-0.28Mn) was developed by condensation polymerization of aniline, followed by catalytic graphitization by Mn. A Pt-based ORR catalyst (Pt/CNF-1300-0.28Mn) was prepared by the ethylene glycol reduction method over polyaniline-based carbon nanofibers. ORR tests showed that Pt/CNF-1300-0.28Mn exhibited much higher activity and stability than the commercial JM-Pt/C catalyst. The half-wave potential of Pt/CNF-1300-0.28Mn exhibited a positive shift of 17 mV relative to that of JM-Pt/C. The mass activity and specific activity were 1.71 and 2.24 times higher than those of commercial Pt/C. After 5 K CV cycles from 1.0 to 1.5 V, the half-wave potential of Pt/CNF-1300-0.28Mn decreased by only 7 mV, much lower than that of JM-Pt/C (16 mV), indicating the excellent corrosion resistance property of the new support. After 20 K CV cycles from 0.60 to 0.95 V, the Pt/CNF-1300-0.28Mn also showed much higher durability than the commercial catalyst. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; METAL-SUPPORT INTERACTION ; DOPED MESOPOROUS CARBON ; EFFICIENT ; PLATINUM ; GRAPHENE ; ELECTROCATALYSTS ; GRAPHITIZATION ; PERFORMANCE ; DURABILITY |
| 资助项目 | Beijing Natural Science Foundation[Z200012] ; Beijing Natural Science Foundation[2202052] ; National Natural Science Foundation of China[92061125] ; National Natural Science Foundation of China[21776014] ; National Natural Science Foundation of China[21975017] ; National Natural Science Foundation of China[51961145107] ; DNL Cooperation Fund, CAS[DNL201921] ; Joint Funds of the National Natural Science Foundation of China[U1705253] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000678221100001 |
| 资助机构 | Beijing Natural Science Foundation ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; Joint Funds of the National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49550]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Chen, Qingjun; Zhu, Hong |
| 作者单位 | 1.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Ganjiang Innovat Acad, Ganzhou 341000, Peoples R China 4.Beijing Univ Chem Technol, Coll Chem, State Key Lab Chem Resource Engn, Dept Organ Chem,Inst Modern Catalysis, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Jinghua,Zhou, Qian,Xue, Xiaoyi,et al. Development of a highly stable Pt-based ORR catalyst over Mn-modified polyaniline-based carbon nanofibers[J]. NEW JOURNAL OF CHEMISTRY,2021:8. |
| APA | Yu, Jinghua.,Zhou, Qian.,Xue, Xiaoyi.,Zhang, Haitao.,Li, Xiaojin.,...&Zhu, Hong.(2021).Development of a highly stable Pt-based ORR catalyst over Mn-modified polyaniline-based carbon nanofibers.NEW JOURNAL OF CHEMISTRY,8. |
| MLA | Yu, Jinghua,et al."Development of a highly stable Pt-based ORR catalyst over Mn-modified polyaniline-based carbon nanofibers".NEW JOURNAL OF CHEMISTRY (2021):8. |
入库方式： OAI收割
来源：过程工程研究所
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