Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol
文献类型：期刊论文
| 作者 | Chen, Shengxin3,4; An, Ran3; Li, Yingwei2,3; Zhu, Yuting1,3; Zhu, Xinbao1; Liu, Ruixia2,3; Li, Xingang4; Zhang, Suojiang2,3,4 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2021-07-21 |
| 卷号 | 60期号:28页码:10112-10118 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.1c01730 |
| 英文摘要 | In recent years, multi-ionic liquids (ILs) mixture systems have been widely noticed and applied in catalysis due to Correction lie their unique properties. In order to establish the quantitative relationship between parameters and catalytic behavior, double salt ILs (DSILs), with different cation (1-ethyl-3-methylimidazolium, choline, tetraethylammonium) but same anion (acetate), are performed in the coupling reaction of propylene oxide (PO) with methanol. In the present work, the DSILs properties like Hammett basicity (H-0), hydrogen bond donor (HBD) ability (alpha), hydrogen bond acceptor (HBA) ability (beta) and dipolarity/polarizability effect (pi*) were considered in the reaction. These control factors were quantitative related to catalytic performance by a modified liner solvent energy relationship (LSER) function that adding a Hammett function correction term. According to the modified LSER, solvents with different parameters were tested to verify its validity and control the reaction. This study demonstrated each parameter could make a different contribution to chemical reaction. It provides a new perspective way for multi-ILs mixture avoiding the intricacies of the parameter relation in ILs catalysis reasonably. |
| WOS关键词 | SOLVATION ENERGY RELATIONSHIPS ; MIXTURES ; CELLULOSE ; SOLVENT ; VALUES ; SCALE ; BETA |
| 资助项目 | National Nature Science Foundation of China[21878315] ; National Key Research and Development Program of China[2017YFA0206803] ; Key Programs of Fujian Institute of Innovation, CAS[FJCXY18020203] ; National Science Fund for Excellent Young Scholars[21722610] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000677542700010 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Nature Science Foundation of China ; National Key Research and Development Program of China ; Key Programs of Fujian Institute of Innovation, CAS ; National Science Fund for Excellent Young Scholars ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49553]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Ruixia; Li, Xingang; Zhang, Suojiang |
| 作者单位 | 1.Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc,CAS Key La, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 4.Tianjin Univ, Natl Engn Res Ctr Distillat Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Shengxin,An, Ran,Li, Yingwei,et al. Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(28):10112-10118. |
| APA | Chen, Shengxin.,An, Ran.,Li, Yingwei.,Zhu, Yuting.,Zhu, Xinbao.,...&Zhang, Suojiang.(2021).Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(28),10112-10118. |
| MLA | Chen, Shengxin,et al."Quantitative Control Factors of Double Salt Ionic Liquids Catalysis in the Coupling Reaction of Epoxied and Methanol".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.28(2021):10112-10118. |
入库方式： OAI收割
来源：过程工程研究所
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