MOF-assisted synthesis of Ni, Co, Zn, and N multidoped porous carbon as highly efficient oxygen reduction electrocatalysts in Zn-air batteries
文献类型：期刊论文
| 作者 | Huang, K.3,4; Rong, C.4; Zhang, W.4; Yang, X.4; Fan, Y.4; Liu, L.4; Yang, Z.4; Chen, W.4; Yang, J.1,2 |
| 刊名 | MATERIALS TODAY ENERGY
 |
| 出版日期 | 2021-03-01 |
| 卷号 | 19页码:10 |
| 关键词 | Oxygen reduction reaction Electrocatalysis Zeolitic imidazolate framework Multidoping Zinc-air battery |
| ISSN号 | 2468-6069 |
| DOI | 10.1016/j.mtener.2020.100579 |
| 英文摘要 | It is an urgent demand to develop cost-effective and efficient non-noble metal electrocatalysts for oxygen reduction reaction (ORR), the key cathodic reaction of fuel cells and metal-air batteries. In this regard, we herein propose a one-pot strategy to produce porous carbon electrocatalysts multidoped by nickel (Ni), cobalt (Co), zinc (Zn), and nitrogen (N). Typically, appropriate metal precursors are aged with 2-methylimidazole in methanol to obtain Ni and Co co-doped Zn-based zeolitic imidazolate frameworks (Ni-Co-ZIF-8) for the final formation of Ni, Co, Zn, and N multi-doped porous carbon (Ni-Co-Zn-N-PC) through pyrolysis, in which cavities and pores are created because of the Zn evaporation at high temperature, while the Co-N bonds in Ni-Co-ZIF-8 could be inherited. The cavities, Co-N active sites and additional synergies among different metals that improve the electrical conductivity of the catalyst collectively promote the ORR catalytic performance of Ni-Co-Zn-N-PC. In specific, the as-prepared Ni-Co-Zn-N-PC features favorable ORR electrocatalysis in a half-wave potential of ca. 0.864 V, limited current density of ca. 6.40 mA cm(-2), superior long-term stability, and strong anti-interference to methanol. In addition, a zinc-air battery using Ni-Co-Zn-N-PC as air-cathode catalyst exhibits good performances in terms of open-circuit voltage, power density, specific capacity, and durability, suggesting its promise in practical energy conversion devices. (C) 2020 Elsevier Ltd. All rights reserved. |
| WOS关键词 | DENSITY-FUNCTIONAL THEORY ; METAL-ORGANIC FRAMEWORK ; ACTIVE-SITES ; GRAPHENE ; CATALYSTS ; FE ; ARCHITECTURE ; NANOSHEETS ; NANOTUBES ; MOSSBAUER |
| 资助项目 | National Natural Science Foundation of China[21463007] ; National Natural Science Foundation of China[22075290] ; Natural Science Foundation of Guangxi Province[2017GXNSFDA198031] ; Natural Science Foundation of Guangxi Province[2019GXNSFGA245003] ; Basic Scientific Research Ability Improvement Project for Young and Middle-aged Teachers of Universities in Guangxi[2020KY39021] ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences[MPCS2017A02] ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences[MPCS2019A09] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000680687000011 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Guangxi Province ; Basic Scientific Research Ability Improvement Project for Young and Middle-aged Teachers of Universities in Guangxi ; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49587]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Fan, Y.; Chen, W.; Yang, J. |
| 作者单位 | 1.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.Guangxi Vocat Tech Inst Ind, Nanning 530001, Peoples R China 4.Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Guangxi Key Lab Low Carbon Energy Mat, Guilin 541004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, K.,Rong, C.,Zhang, W.,et al. MOF-assisted synthesis of Ni, Co, Zn, and N multidoped porous carbon as highly efficient oxygen reduction electrocatalysts in Zn-air batteries[J]. MATERIALS TODAY ENERGY,2021,19:10. |
| APA | Huang, K..,Rong, C..,Zhang, W..,Yang, X..,Fan, Y..,...&Yang, J..(2021).MOF-assisted synthesis of Ni, Co, Zn, and N multidoped porous carbon as highly efficient oxygen reduction electrocatalysts in Zn-air batteries.MATERIALS TODAY ENERGY,19,10. |
| MLA | Huang, K.,et al."MOF-assisted synthesis of Ni, Co, Zn, and N multidoped porous carbon as highly efficient oxygen reduction electrocatalysts in Zn-air batteries".MATERIALS TODAY ENERGY 19(2021):10. |
入库方式： OAI收割
来源：过程工程研究所
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