Upgrading of palmitic acid to diesel-like fuels over Ni@HZSM-5 bi-functional catalysts through the in situ encapsulation method
文献类型：期刊论文
| 作者 | Gao, Chen1,3; Zhang, Jimei1,3; Xing, Enhui2; Xie, Yongbing3; Zhao, He3; Ning, Pengge3; Shi, Yanchun3 |
| 刊名 | MOLECULAR CATALYSIS
 |
| 出版日期 | 2021-07-01 |
| 卷号 | 511页码:12 |
| 关键词 | Palmitic acid Ni@HZSM-5 Diesel-like fuels Encapsulation Low Ni content |
| ISSN号 | 2468-8231 |
| DOI | 10.1016/j.mcat.2021.111715 |
| 英文摘要 | Ni@HZSM-5 bi-functional catalysts were successfully synthesized through the in situ encapsulation method to form 2-5 nm Ni nanoparticles within HZSM-5 crystals, which was applied in evaluating the hydrodeoxygenation performance of palmitic acid to diesel-like range fuels. As for Ni@HZSM-5, there was the certain interaction between Ni and Al, which further influenced the hydrogenation activity and acidity of catalysts. Complete deoxygenation of palmitic acid and 100% selectivity of alkanes were achieved over Ni@HZSM-5 bi-functional catalysts, and the corresponding main products were C15 and C16 alkanes. Importantly, Ni@HZSM-5 (2.4 wt% Ni) exhibited the high conversion activity of 16.4 mol((palmitic acid)) .mol((Ni))(-1) .h(-1), which were attributed to 2-5 nm Ni nanoparticles uniformly dispersed within HZSM-5 crystals. Ni@HZSM-5 further exhibited the well catalytic stability during the process of regeneration and recycle runs without obvious change of Ni sizes and dispersion, which was totally different from impregnated Ni/HZSM-5 catalysts with the aggregation of Ni particles. The favorable performance of Ni@HZSM-5 was ascribed to small Ni nanoparticles within HZSM-5 crystals without any obvious aggregation, which would offer a novel strategy for synthesizing low metal@zeolite bi-functional catalysts with high activity and stability in upgrading of bio-mass oils. |
| WOS关键词 | SPINEL-TYPE CATALYSTS ; SELECTIVE HYDROGENATION ; FATTY-ACIDS ; PHASE HYDRODEOXYGENATION ; RENEWABLE DIESEL ; RAPESEED OIL ; ISO-ALKANES ; OLEIC-ACID ; ZEOLITE ; NANOPARTICLES |
| 资助项目 | National Natural Science Foundation of China[21908225] ; Science and Technology Service Network Initiative[KFJ-STS-QYZD-081] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000681472000006 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Science and Technology Service Network Initiative |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49599]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Shi, Yanchun |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Sinopec, State Key Lab Catalyt Mat & React Engn, Res Inst Petr Proc, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Inst Proc Engn, Div Environm Engn & Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Chen,Zhang, Jimei,Xing, Enhui,et al. Upgrading of palmitic acid to diesel-like fuels over Ni@HZSM-5 bi-functional catalysts through the in situ encapsulation method[J]. MOLECULAR CATALYSIS,2021,511:12. |
| APA | Gao, Chen.,Zhang, Jimei.,Xing, Enhui.,Xie, Yongbing.,Zhao, He.,...&Shi, Yanchun.(2021).Upgrading of palmitic acid to diesel-like fuels over Ni@HZSM-5 bi-functional catalysts through the in situ encapsulation method.MOLECULAR CATALYSIS,511,12. |
| MLA | Gao, Chen,et al."Upgrading of palmitic acid to diesel-like fuels over Ni@HZSM-5 bi-functional catalysts through the in situ encapsulation method".MOLECULAR CATALYSIS 511(2021):12. |
入库方式： OAI收割
来源：过程工程研究所
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