中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
NiCo2N hollow sphere with interconnected nanosheets shell: A potential anode material for high performance lithium-ion batteries

文献类型:期刊论文

作者Wang, Peiyao1,2; Bai, Jin2; Li, Kunzhen1,2; Ma, Hongyang1,2; Li, Wanyun1,2; Zhu, Xuebin2; Sun, Yuping2,3; Zhao, Bangchuan2
刊名CHEMICAL ENGINEERING JOURNAL
出版日期2021-12-01
卷号425
关键词NiCo2N Hollow structure Interconnected nanosheets Lithium-ion batteries
ISSN号1385-8947
DOI10.1016/j.cej.2021.130607
通讯作者Bai, Jin(jbai@issp.ac.cn) ; Zhao, Bangchuan(bchzhao@issp.ac.cn)
英文摘要Transition metal nitrides are of great interest for lithium storage application due to their high electrical conductivity and low voltage plateau. However, the relative cycling stability restricts their practical application. Herein, a stable bimetal nitride NiCo2N hollow sphere material with interconnected nanosheets shell was successfully synthesized via a facial solvothermal route. When used as anodes for lithium-ion batteries, the unique structure can effectively relieve the volume change of the electrode material, and shorten the diffusion distance of lithium ions during the repeated cycling processes. As a result, the NiCo2N electrode exhibits an excellent electrochemical performance. It delivers high discharge capacity of 1244.5 mAh g(-1) at a current density of 1 A g(-1) after 400 cycles, the capacity can maintain 529.4 mAh g(-1) at high current density of 5 A g(-1). Furthermore, the electrochemical reaction mechanism of the electrodes is revealed by ex situ XRD, ex situ EIS, and ex situ HRTEM characterization.
WOS关键词COBALT NITRIDE ; CARBON NANOSHEET ; ENERGY-STORAGE ; CATALYST ; OXIDE
资助项目National Key Research and Development Program[2017YFA0402800] ; National Natural Science Foundation of China[U1732160]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000728515300001
出版者ELSEVIER SCIENCE SA
资助机构National Key Research and Development Program ; National Natural Science Foundation of China
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/126420]  
专题中国科学院合肥物质科学研究院
通讯作者Bai, Jin; Zhao, Bangchuan
作者单位1.Univ Sci & Technol China, Hefei 230026, Peoples R China
2.Chinese Acad Sci, HFIPS, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
3.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Peoples R China
推荐引用方式
GB/T 7714
Wang, Peiyao,Bai, Jin,Li, Kunzhen,et al. NiCo2N hollow sphere with interconnected nanosheets shell: A potential anode material for high performance lithium-ion batteries[J]. CHEMICAL ENGINEERING JOURNAL,2021,425.
APA Wang, Peiyao.,Bai, Jin.,Li, Kunzhen.,Ma, Hongyang.,Li, Wanyun.,...&Zhao, Bangchuan.(2021).NiCo2N hollow sphere with interconnected nanosheets shell: A potential anode material for high performance lithium-ion batteries.CHEMICAL ENGINEERING JOURNAL,425.
MLA Wang, Peiyao,et al."NiCo2N hollow sphere with interconnected nanosheets shell: A potential anode material for high performance lithium-ion batteries".CHEMICAL ENGINEERING JOURNAL 425(2021).

入库方式: OAI收割

来源:合肥物质科学研究院

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。