Anchoring CsPbI3 crystalline for stable and efficient perovskite solar cells with perfluorocarbon-assisted shield
文献类型:期刊论文
作者 | Zhang, Liying1,3; Liu, Boyuan1,3; Xu, Xiaoxiao1,3; Xu, Shendong1,3; Du, Du1,2; Zhang, Hui1,2; Guo, Tianle1,2; Zheng, Haiying2; Liu, Guozhen1; Pan, Xu1 |
刊名 | SOLAR ENERGY |
出版日期 | 2021-11-01 |
卷号 | 228 |
ISSN号 | 0038-092X |
关键词 | Perovskite solar cells Cesium lead iodide Perfluorocarbon Defect passivation Stability |
DOI | 10.1016/j.solener.2021.10.009 |
通讯作者 | Liu, Guozhen(gzliu@issp.ac.cn) |
英文摘要 | The inorganic perovskite solar cells (PSCs) are now playing an increasingly essential role in the realm of clean energy. However, the application of inorganic perovskite solar cells is usually limited as the spontaneous phase transform. Here, we applied the 1H, 1H-Perfluorooctylammonium iodide (PFOAI) upon the surface of the cesium lead iodide (CsPbI3) films by taking advantage of its excellent defect passivation ability and hydrophobicity. Decreased recombination upon the surface and postponed degradation of the device were achieved for the observation of lower trap density and longer carrier lifetime and better stability based on the PFOAI-CsPbI3 films. The champion PFOAI-CsPbI3 based device showed an increased power conversion efficiency (PCE) of 18.24% with the excellent fill factor (FF) of 81.77% and Jsc of 20.51 mA cm(-2) and remain similar to 85% of its initial PCE for 1000 h (25 degrees C) in the N-2 glovebox. This work adds slightly weight on the balance of balancing the stability and high efficiency of the inorganic PSCs. |
WOS关键词 | ALPHA-CSPBI3 PEROVSKITE ; STABILITY |
资助项目 | CASHIPS Director's Fund[YZJJ2021QN20] ; National Natural Foundation of Anhui Province[2008085QE208] |
WOS研究方向 | Energy & Fuels |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000716395800003 |
资助机构 | CASHIPS Director's Fund ; National Natural Foundation of Anhui Province |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/126686] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Liu, Guozhen |
作者单位 | 1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Solid State Phys, Key Lab Photovolta & Energy Conservat Mat, Hefei 230031, Peoples R China 2.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Peoples R China 3.Univ Sci & Technol China, Hefei 230026, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Liying,Liu, Boyuan,Xu, Xiaoxiao,et al. Anchoring CsPbI3 crystalline for stable and efficient perovskite solar cells with perfluorocarbon-assisted shield[J]. SOLAR ENERGY,2021,228. |
APA | Zhang, Liying.,Liu, Boyuan.,Xu, Xiaoxiao.,Xu, Shendong.,Du, Du.,...&Pan, Xu.(2021).Anchoring CsPbI3 crystalline for stable and efficient perovskite solar cells with perfluorocarbon-assisted shield.SOLAR ENERGY,228. |
MLA | Zhang, Liying,et al."Anchoring CsPbI3 crystalline for stable and efficient perovskite solar cells with perfluorocarbon-assisted shield".SOLAR ENERGY 228(2021). |
入库方式: OAI收割
来源:合肥物质科学研究院
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