Particle Size and Particle-Size Distribution Effects on Li+ Extraction/Insertion Kinetics for Li-Rich Mn-Based Oxides
文献类型：期刊论文
| 作者 | Fang, Zhitang2; Li, Wanyun1,2; Zhao, Bangchuan2 ; Bai, Jin2; Li, Kunzhen2; Ma, Hongyang1,2; Zhu, Xuebin2; Sun, Yuping2,3
|
| 刊名 | ACS APPLIED ENERGY MATERIALS
 |
| 出版日期 | 2021-09-28 |
| 卷号 | 4 |
| 关键词 | Li1.2Ni0.13Co0.13Mn0.54O2 manganese sources particle size particle-size distribution electrochemical kinetics |
| ISSN号 | 2574-0962 |
| DOI | 10.1021/acsaem.1c01941 |
| 通讯作者 | Zhao, Bangchuan(bchzhao@issp.ac.cn) |
| 英文摘要 | A series of Li-rich Mn-based layered material Li1.2Ni0.13Co0.13Mn0.54O2 (LMR) with different particle sizes and particle-size distributions (PSDs) have been successfully synthesized via a combustion method using different manganese sources. The particle size of the N-LMR material prepared using Mn(NO3)(2)center dot 4H(2)O as the manganese source is the smallest, and its PSD range is the narrowest among all of the samples. The unique particle size and PSD have a great influence on the electrochemical kinetics of Li-ion extraction/insertion reactions, leading to enhanced electrochemical performance when used as a cathode material for both the half and full Li-ion cells, especially the specific charge capacity at high current rates. The value of the charge specific capacity will determine the state of charge at the initial discharge stage and then influence the discharge process of these Li-rich Mn-based oxides. The N-LMR electrode delivers an initial discharge capacity of 309.2 mA h g(-1) at 0.1C, and the specific capacity can reach up to 208.1 mA h g(-1) at 1C. After 140 cycles, the electrode can still maintain 95.6% of its initial specific capacity at 1C. Moreover, the material displays a superior high-temperature lithium storage property at 55 degrees C and the full cells using N-LMR as the cathode material also show a much better electrochemical performance. |
| WOS关键词 | SOLUTION COMBUSTION SYNTHESIS ; CATHODE MATERIALS ; ELECTROCHEMICAL PERFORMANCE ; ION BATTERIES ; LAYERED OXIDE ; HIGH-CAPACITY ; MICROSPHERES ; STABILITY ; STRATEGY ; PROGRESS |
| 资助项目 | National Key Research and Development program[2017YFA0402800] ; Users with Excellence Program of Hefei Science Center CAS[2021HSC-UE009] ; National Natural Science Foundation of China[U1732160] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000711236300059 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key Research and Development program ; Users with Excellence Program of Hefei Science Center CAS ; National Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/126696]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Zhao, Bangchuan |
| 作者单位 | 1.Univ Sci & Technol China, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, HFIPS, Hefei 230031, Peoples R China 3.Chinese Acad Sci, High Magnet Field Lab, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Zhitang,Li, Wanyun,Zhao, Bangchuan,et al. Particle Size and Particle-Size Distribution Effects on Li+ Extraction/Insertion Kinetics for Li-Rich Mn-Based Oxides[J]. ACS APPLIED ENERGY MATERIALS,2021,4. |
| APA | Fang, Zhitang.,Li, Wanyun.,Zhao, Bangchuan.,Bai, Jin.,Li, Kunzhen.,...&Sun, Yuping.(2021).Particle Size and Particle-Size Distribution Effects on Li+ Extraction/Insertion Kinetics for Li-Rich Mn-Based Oxides.ACS APPLIED ENERGY MATERIALS,4. |
| MLA | Fang, Zhitang,et al."Particle Size and Particle-Size Distribution Effects on Li+ Extraction/Insertion Kinetics for Li-Rich Mn-Based Oxides".ACS APPLIED ENERGY MATERIALS 4(2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。