Laser-assisted high-performance PtRu alloy for pH-universal hydrogen evolution
文献类型：期刊论文
| 作者 | Pang, Beibei1; Liu, Xiaokang1; Liu, Tianyang2; Chen, Tao1,3; Shen, Xinyi1; Zhang, Wei1; Wang, Sicong1; Liu, Tong1; Liu, Dong1; Ding, Tao1 |
| 刊名 | ENERGY & ENVIRONMENTAL SCIENCE
 |
| 出版日期 | 2021-11-24 |
| ISSN号 | 1754-5692 |
| DOI | 10.1039/d1ee02518j |
| 通讯作者 | Li, Yafei(liyafie@njnu.edu.cn) ; Liang, Changhao(chliang@issp.ac.cn) ; Yao, Tao(yaot@ustc.edu.cn) |
| 英文摘要 | Elucidating the interaction between different atomic species of bimetallic nanoparticles under reaction conditions is the key to the design of efficient catalysts. Here, we report a laser-assisted strategy towards PtRu alloys, where isolated Pt sites are anchored on the Ru host, and track the variation of the active site under electrocatalytic conditions. Operando X-ray absorption spectroscopy identified the local environment variations around Pt single atoms and revealed the increased PtRu alloying degree during the hydrogen evolution reaction (HER). Theoretical simulations confirmed that the increase of alloying extent modulates the d-band center of Ru for enhancing the activity. Surface-restructured PtRu alloy exhibited outstanding HER activity and stability under all pH values, achieving an unexpected low overpotential of only 15, 17, and 28 mV at 10 mA cm(-2) in 1 M KOH, 1 M PBS, and 0.5 M H2SO4, respectively. This demonstrates the feasibility of surface engineering for designing advanced bimetallic catalysts with atomic-scale platinum decoration. |
| WOS关键词 | SELECTIVE HYDROGENATION ; CATALYSTS ; ATOM ; NANOPARTICLES ; EFFICIENT ; NANOTUBES ; OXIDATION ; SILICA |
| 资助项目 | China Ministry of Science and Technology[2021YFA1600800] ; China Ministry of Science and Technology[2017YFA0208300] ; China Ministry of Science and Technology[2020YFA0710200] ; National Natural Science Foundation of China[12025505] ; National Natural Science Foundation of China[52071313] ; Youth Innovation Promotion Association CAS[CX2310007007] ; Youth Innovation Promotion Association CAS[CX2310000091] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000727437400001 |
| 资助机构 | China Ministry of Science and Technology ; National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/126786]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Li, Yafei; Liang, Changhao; Yao, Tao |
| 作者单位 | 1.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China 2.Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China 3.Southwest Univ Sci & Technol, Sch Natl Def Sci & Technol, Mianyang 621010, Sichuan, Peoples R China 4.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Key Lab Mat Phys, Hefei 230031, Peoples R China 5.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Anhui Key Lab Nanomat & Nanotechnol, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pang, Beibei,Liu, Xiaokang,Liu, Tianyang,et al. Laser-assisted high-performance PtRu alloy for pH-universal hydrogen evolution[J]. ENERGY & ENVIRONMENTAL SCIENCE,2021. |
| APA | Pang, Beibei.,Liu, Xiaokang.,Liu, Tianyang.,Chen, Tao.,Shen, Xinyi.,...&Yao, Tao.(2021).Laser-assisted high-performance PtRu alloy for pH-universal hydrogen evolution.ENERGY & ENVIRONMENTAL SCIENCE. |
| MLA | Pang, Beibei,et al."Laser-assisted high-performance PtRu alloy for pH-universal hydrogen evolution".ENERGY & ENVIRONMENTAL SCIENCE (2021). |
入库方式： OAI收割
来源：合肥物质科学研究院
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