中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)

文献类型:期刊论文

作者Lu, Chao; Zhang, Bo; Zhang, Hua2; Guo, Yun; Dang, Leping; Liu, Zhengan3; Shu, Qingyan3; Wang, Zhanzhong
刊名INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
出版日期2019
卷号58期号:23页码:10044-10052
ISSN号0888-5885
DOI10.1021/acs.iecr.9b01947
文献子类Article
英文摘要The crystallization and melting behaviors of binary tripalmitoylglycerol (PPP)/1,2-dioleoyl-3-palmitoyl glycerol (P00), tripalmitoylglycerol (PPP)/1,3-dipalmitoy1-2-oleoyl glycerol (POP), and 1,3-dipalmitoyl-2-oleoyl glycerol (POP)/1,2dioleoy1-3-palmitoyl glycerol (P00) were investigated using differential scanning calorimetry (DSC). On the basis of melting phase equilibrium data, solid-liquid phase diagrams of binary systems (PPP/P00, PPP/POP, and POP/P00) were constructed. With respect to PPP/POO and PPP/POP, eutectic and solid solution phase equilibrium were confirmed when PPP content (X-PPP) in the mixtures was lower and higher than 90% and 80% (w/w), respectively. For POP/P00, the solid solution and eutectic phase equilibrium were confirmed when the POP content (X-POP) in the mixtures was lower and higher than 80% (w/w), respectively. Interestingly, polymorphic transition behaviors of PPP, POP, and POO at melting stages were also revealed. Finally, melting Gibbs free energy changes based on enthalpy changes for different binary mixtures were predicted by thermodynamics models.
学科主题Engineering, Chemical
出版地WASHINGTON
WOS关键词DIFFERENTIAL SCANNING CALORIMETRY ; PALM OIL ; FATTY-ACIDS ; CRYSTALLIZATION ; TRIGLYCERIDES ; SYSTEMS
WOS研究方向Engineering
语种英语
WOS记录号WOS:000471835000030
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21676196] ; Tianjin Municipal Natural Science FoundationNatural Science Foundation of Tianjin [17JCYBJC20400]
源URL[http://ir.ibcas.ac.cn/handle/2S10CLM1/19485]  
专题中科院北方资源植物重点实验室
作者单位1.Chongqing Inst Food & Drug Control, Chongqing 401121, Peoples R China
2.Chinese Acad Sci, Inst Bot, Beijing Bot Garden, Key Lab Plant Resources, Beijing 100093, Peoples R China
3.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714
Lu, Chao,Zhang, Bo,Zhang, Hua,et al. Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(23):10044-10052.
APA Lu, Chao.,Zhang, Bo.,Zhang, Hua.,Guo, Yun.,Dang, Leping.,...&Wang, Zhanzhong.(2019).Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO).INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(23),10044-10052.
MLA Lu, Chao,et al."Solid-Liquid Phase Equilibrium and Phase Behaviors for Binary Mixtures Composed of Tripalmitoylglycerol (PPP), 1,3-Dipalmitoyl-2-oleoyl-glycerol (POP), and 1,2-Dioleoyl-3-palmitoyl-glycerol (POO)".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.23(2019):10044-10052.

入库方式: OAI收割

来源:植物研究所

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