A manganese(ii) phthalocyanine under water-oxidation reaction: new findings
文献类型：期刊论文
| 作者 | Mousazade, Younes; Najafpour, Mohammad Mahdi1,6; Bagheri, Robabeh5; Jaglicic, Zvonko15,16; Singh, Jitendra Pal14; Chae, Keun Hwa14; Song, Zhenlun5; Rodionova, Margarita V.; Voloshin, Roman A.; Shen, Jian-Ren
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| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2019 |
| 卷号 | 48期号:32页码:12147-12158 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c9dt01790a |
| 文献子类 | Article |
| 英文摘要 | Phthalocyanines are a promising class of ligands for manganese because of their high binding affinity. This effect is suggested to be an important factor because phthalocyanines tightly bind manganese and stabilize it under moderate conditions. The strong donor power of phthalocyanine is also suggested as a critical factor to stabilize high-valent manganese phthalocyanine. Herein, a manganese(ii) phthalocyanine, which is stable under moderate conditions, was investigated under harsh electrochemical water oxidation. By scanning electron microscopy, transmission electron microscopy, energy dispersive spectrometry, X-ray diffraction, extended X-ray absorption fine structure analysis, X-ray absorption near edge structure analysis, chronoamperometry, magnetic measurements, Fourier-transform infrared spectroscopy, and electrochemical methods, it is shown that manganese phthalocyanine, a known molecular complex showing good stability under moderate conditions, could not withstand water oxidation catalysis and ultimately is altered to form catalytic oxide particles. Such nanosized Mn oxides are the true catalyst for water oxidation. Besides, we try to go a step forward to find an answer as to how Mn oxides form on the surface of the electrode. |
| 学科主题 | Chemistry, Inorganic & Nuclear |
| 出版地 | CAMBRIDGE |
| 电子版国际标准刊号 | 1477-9234 |
| WOS关键词 | EVOLVING PHOTOSYSTEM-II ; OXIDIZING CATALYSTS ; MN OXIDES ; COMPLEX ; EFFICIENT ; METAL ; NANO ; ELECTROCHEMISTRY ; POTENTIALS ; MECHANISM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000480592500014 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Iranian National Science Foundation (INSF)Iran National Science Foundation (INSF) [96003636] ; Russian Science FoundationRussian Science Foundation (RSF) [19-14-00118] ; Slovenian Research AgencySlovenian Research Agency - Slovenia [P2-0348] ; Ningbo Institute of Materials Technology ; Korea Institute of Science and Technology (KIST)Korea Institute of Science & Technology (KIST) |
| 源URL | [http://ir.ibcas.ac.cn/handle/2S10CLM1/19549]  |
| 专题 | 中科院光生物学重点实验室 |
| 作者单位 | 1.IASBS, Dept Chem, Zanjan 4513766731, Iran 2.Allakhverdiev, Suleyman I.] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia 3.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142290, Moscow Region, Russia 4.Allakhverdiev, Suleyman I.] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan 5.IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran 6.IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran 7.Allakhverdiev, Suleyman I.] Moscow MV Lomonosov State Univ, Fac Biol, Dept Plant Physiol, Leninskie Gory 1-12, Moscow 119991, Russia 8.Natl Univ Singapore, Ctr Nanofibers & Nanotechnol, Dept Mech Engn, Singapore 117576, Singapore 9.Chinese Acad Sci, Inst Bot, Key Lab Photobiol, Photosynth Res Ctr, 20 Nanxincun, Beijing 100093, Peoples R China 10.Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan |
| 推荐引用方式 GB/T 7714 | Mousazade, Younes,Najafpour, Mohammad Mahdi,Bagheri, Robabeh,et al. A manganese(ii) phthalocyanine under water-oxidation reaction: new findings[J]. DALTON TRANSACTIONS,2019,48(32):12147-12158. |
| APA | Mousazade, Younes.,Najafpour, Mohammad Mahdi.,Bagheri, Robabeh.,Jaglicic, Zvonko.,Singh, Jitendra Pal.,...&Allakhverdiev, Suleyman I..(2019).A manganese(ii) phthalocyanine under water-oxidation reaction: new findings.DALTON TRANSACTIONS,48(32),12147-12158. |
| MLA | Mousazade, Younes,et al."A manganese(ii) phthalocyanine under water-oxidation reaction: new findings".DALTON TRANSACTIONS 48.32(2019):12147-12158. |
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来源：植物研究所
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