Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12
文献类型：期刊论文
| 作者 | Li Junjie ; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
|
| 刊名 | Solid State Sciences
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:5页码:966-969 |
| 关键词 | Pb6b2wo12 Boratotungstate Structure Determination Single-crystal Diffraction |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2011.02.008 |
| 英文摘要 | A novel boratotungstate, Pb6B2WO12, has been prepared by solid-state reaction. The single-crystal X-ray structural analysis showed that Pb6B2WO12 crystallizes in the orthorhombic space group Cmcm (No. 63) with a = 18.4904(5) , b = 6.35980(10) , c = 11.6789(2) , Z = 4 and R1 = 0.0253, wR2 = 0.0557. The compound is characterized by one-dimensional (Pb3O)∞1 chains formed by corner-sharing OPb4 tetrahedra. BO3 and WO4 groups are located around the chains to hold them together via Pb-O bonds. The IR spectra further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb6B2WO 12 is a congruently melting compound. |
| 学科主题 | Chemistry ; Physics |
| WOS记录号 | WOS:000291081900024 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1429]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Pan Shilie |
| 作者单位 | Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12[J]. Solid State Sciences,2011,13(5):966-969. |
| APA | Li Junjie,Pan Shilie,Zhao Wenwu,Tian Xuelin,Han Jian,&Fan Xiaoyun.(2011).Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12.Solid State Sciences,13(5),966-969. |
| MLA | Li Junjie,et al."Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12".Solid State Sciences 13.5(2011):966-969. |
入库方式： OAI收割
来源：新疆理化技术研究所
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