Ferrocene modified g-C(3)N(4 )as a heterogeneous catalyst for photo-assisted activation of persulfate for the degradation of tetracycline
文献类型：期刊论文
| 作者 | Wang, Zixuan1,2; Wang, Han1,2; Wang, Ziwei1,2; Huang, Danlian1,2; Qin, Hong1,2; He, Yangzhuo1,2; Chen, Ming3; Zeng, Guangming1,2; Xu, Piao1,2 |
| 刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
 |
| 出版日期 | 2021-10-05 |
| 卷号 | 626页码:14 |
| ISSN号 | 0927-7757 |
| 关键词 | Tetracycline degradation Persulfate Photocatalytic activation Ferrocene modification |
| DOI | 10.1016/j.colsurfa.2021.127024 |
| 通讯作者 | Chen, Ming(mchensen@hnu.edu.cn) ; Zeng, Guangming(zgming@hnu.edu.cn) ; Xu, Piao(piaoxu@hnu.edu.cn) |
| 英文摘要 | In this study, the oxidative degradation of tetracycline (TC) by ferrocene-modified graphite phase carbon nitride (Fe/g-C3N4) activated persulfate (PS) under light-assisted conditions is examined. The materials are characterized by a series of methods such as SEM, TEM, XRD, FTIR, XPS, etc. This article explores the influence of the amount of sulfate, the initial concentration of pollutants, the amount of catalyst, and the pH value on the reaction system. When the amount of PS added reaches 2.5 mM and the catalyst dosage is 1 g L-1, the Fe/g-C3N4/PS/Vis exhibit the best performance for tetracycline removal. In 60 min, the removal of tetracycline reaches 93% under its natural pH. In the reaction system acidic neutral conditions are more conducive to degrade TC. The results show that the doping of ferrocene inhibits the recombination of electron-hole pairs in the g-C3N4, expands the light response range to speed up the removal rate of tetracycline. At the same time, iron cycle generated by ferrocene modification helps to activate persulfate to produce sulfate radicals with strong oxidizing properties. Sulfate radicals, hydroxyl radicals, superoxide radicals and holes are the main active species proved by ESR test and the quenching experiments. The synergy between photocatalysis and PS activation promotes the production of active species and the tetracycline removal. The results show that the Fe/g-C3N4 composite material activated persulfate under visible light is an effective method to remove tetracycline from water. |
| 资助项目 | National Natural Science Foundation of China[51521006] ; National Natural Science Foundation of China[51378190] ; National Natural Science Foundation of China[51039001] ; National Natural Science Foundation of China[50179011] ; National Natural Science Foundation of China[51709101] ; National Natural Science Foundation of China[51879101] ; National Natural Science Foundation of China[51579098] ; National Program for Support of Top-Notch Young Professionals of China (2014) ; Program for Changjiang Scholars and Innovative Research Team in University[IRT13R17] ; Hunan Provincial Science and Technology Plan Project[2018SK20410] ; Hunan Provincial Science and Technology Plan Project[2017SK2243] ; Hunan Provincial Science and Technology Plan Project[2016RS3026] ; Fundamental Research Funds for the Central Universities[531119200086] ; Fundamental Research Funds for the Central Universities[531118010114] ; Fundamental Research Funds for the Central Universities[531107050978] ; Fundamental Research Funds for the Central Universities[541109060031] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000685962600003 |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/13900]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Chen, Ming; Zeng, Guangming; Xu, Piao |
| 作者单位 | 1.Hunan Univ, Key Lab Environm Biol & Pollut Control, Minist Educ, Changsha 410082, Peoples R China 2.Hunan Univ, Coll Environm Sci & Engn, Changsha 410082, Peoples R China 3.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Key Lab Reservoir Aquat Environm, Chongqing 400714, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zixuan,Wang, Han,Wang, Ziwei,et al. Ferrocene modified g-C(3)N(4 )as a heterogeneous catalyst for photo-assisted activation of persulfate for the degradation of tetracycline[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2021,626:14. |
| APA | Wang, Zixuan.,Wang, Han.,Wang, Ziwei.,Huang, Danlian.,Qin, Hong.,...&Xu, Piao.(2021).Ferrocene modified g-C(3)N(4 )as a heterogeneous catalyst for photo-assisted activation of persulfate for the degradation of tetracycline.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,626,14. |
| MLA | Wang, Zixuan,et al."Ferrocene modified g-C(3)N(4 )as a heterogeneous catalyst for photo-assisted activation of persulfate for the degradation of tetracycline".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 626(2021):14. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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