Sandwich-like MoO3/ZnCo2O4 QDs@C@rGO/MoO3 hybrid nanosheets as high-performance anode for lithium-ion batteries
文献类型：期刊论文
| 作者 | Liang, Wenfei1,2; Zhong, Linping1; Quan, Lijun1; Wang, Xuejia1; Liu, Mengjiao1; Lai, Xin1; Bi, Jian1; Gao, Daojiang1; Liu, Xiaohong2; Zhang, Wei2
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| 刊名 | CERAMICS INTERNATIONAL
 |
| 出版日期 | 2021-11-15 |
| 卷号 | 47期号:22页码:32118-32129 |
| ISSN号 | 0272-8842 |
| 关键词 | Transition metal oxides anode Sandwich-like structure Multi-porous nanostructure ZnCo2O4 quantum dots Electrochemical performance |
| DOI | 10.1016/j.ceramint.2021.08.103 |
| 通讯作者 | Liu, Mengjiao(liumengjiao@sicnu.edu.cn) ; Zhao, Yan(zhaoyan@sicnu.edu.cn) |
| 英文摘要 | Transition metal oxides (TMOs) based compounds are recognized as high-energy anodes in next-generation lithium-ion batteries (LIBs) due to their extremely high theoretical capacity. However, the lower intrinsic conductivity, fast fading cyclic stability and dramatic volume expansion during discharge/charge processes greatly hinder the practical application of TMOs as anodes in LIBs. In this study, we have designed and constructed MoO3/ZnCo2O4 QDs@C@rGO/MoO3 (denoted as GMZCO) sandwich-structured hybrid nanocomposites via an effective route, and have proposed the formation mechanism of this unique nanostructured composite on the basis of the systematic results of the microstructures. Due to the unique sandwich structure and the synergistic enhancement effect of the ZnCo2O4 QDs, alpha-MoO3 and rGO, the as-constructed GMZCO exhibits the superior electrochemical performances when used as anode for LIBs. The obtained GMZCO can maintain high capacity of 1281 mAh g(-1) at 0.2 A g(-1) after 300 cycles, and can deliver as high as specific capacity of 913 mAh g(-1) at 1 A g(-1) after 500 cycles, revealing the higher capacity and excellent cyclic stability. What deserves to be mentioned most is that GMZCO can keep a capacity of 541 mAh g(-1) after 1400 cycles even at higher current density of 3 A g(-1) crostructures as a promising anode for the high-performances LIBs. , having outstanding rate capability. This work paves a novel approach for design TMOs with unique microstructures as a promising anode for the high-performances LIBs. |
| 资助项目 | Sichuan Science and Technology Program[2019YJ0525] ; Scientific Research Fund of Sichuan Provincial Education Department of Sichuan Province[16TD0007] ; Open Foundation of Key Laboratory of Sichuan Province Higher Education Systems[SWWT2016-3] ; Youth Innovation Promotion Association of CAS[2015316] |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000703985500001 |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/14093]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Liu, Mengjiao; Zhao, Yan |
| 作者单位 | 1.Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610066, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Wenfei,Zhong, Linping,Quan, Lijun,et al. Sandwich-like MoO3/ZnCo2O4 QDs@C@rGO/MoO3 hybrid nanosheets as high-performance anode for lithium-ion batteries[J]. CERAMICS INTERNATIONAL,2021,47(22):32118-32129. |
| APA | Liang, Wenfei.,Zhong, Linping.,Quan, Lijun.,Wang, Xuejia.,Liu, Mengjiao.,...&Zhao, Yan.(2021).Sandwich-like MoO3/ZnCo2O4 QDs@C@rGO/MoO3 hybrid nanosheets as high-performance anode for lithium-ion batteries.CERAMICS INTERNATIONAL,47(22),32118-32129. |
| MLA | Liang, Wenfei,et al."Sandwich-like MoO3/ZnCo2O4 QDs@C@rGO/MoO3 hybrid nanosheets as high-performance anode for lithium-ion batteries".CERAMICS INTERNATIONAL 47.22(2021):32118-32129. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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