Fabrication of a honeycomb-like bimetallic SERS substrate for the detection of triphenyltin chloride
文献类型：期刊论文
| 作者 | Jiang, Shan2,3; Chang, Lin2,3; Luo, Jie4,5; Zhang, Jianfa4,5; Liu, Xiaohong2; Lee, Chong-Yew1; Zhang, Wei2,3
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| 刊名 | ANALYST
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| 出版日期 | 2021-08-31 |
| 页码 | 8 |
| ISSN号 | 0003-2654 |
| DOI | 10.1039/d1an01359a |
| 通讯作者 | Zhang, Wei(andyzhangwei@163.com) |
| 英文摘要 | Triphenyltin chloride (TPhT) is an organotin compound that causes intensive toxicological risk to the environment and humans. A detection method with high sensitivity and stability is therefore desired to better detect TPhT. In this study, a novel SERS substrate was prepared by sputtering an ultra-thin Au layer on a honeycomb-like silver nanoarray fabricated via the nanosphere lithography method. The ultra-thin Au layer was formed by sputtering the intermittent Au nanoparticles on the silver nanoarray, resulting in bimetallic coupling with dramatically increased hotspots and extremely high SERS enhancement with an analytical enhancement factor (AEF) of 6.08 x 10(9) using Rhodamine 6G (R6G) as the probe molecule. Based on density functional theory (DFT) simulations, the Raman characteristic peaks of TPhT at 999 cm(-1) and 655 cm(-1) were selected for TPhT detection. The AEF of the SERS substrate HC5-AgAu was calculated to be 3.38 x 10(6) with the detection concentration of TPhT down to 10(-10) M. The as-prepared honeycomb-like silver-gold bimetallic SERS substrate demonstrated great stability and sensitivity for TPhT detection, which might also be applied in monitoring many other environmental pollutants. |
| 资助项目 | National Natural Science Foundation of China[61575196] ; National Natural Science Foundation of China[62175237] ; Chongqing Talents Program[CQYC201905041] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000695847400001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/14267]  |
| 专题 | 中国科学院重庆绿色智能技术研究院 |
| 通讯作者 | Zhang, Wei |
| 作者单位 | 1.Univ Sains Malaysia, Sch Pharmaceut Sci, Gelugor 11800, Penang, Malaysia 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 3.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China 4.Natl Univ Def Technol, Coll Adv Interdisciplinary Studies, Changsha 410073, Peoples R China 5.Natl Univ Def Technol, Hunan Prov Key Lab Novel Nanooptoelect Informat M, Changsha 410073, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Shan,Chang, Lin,Luo, Jie,et al. Fabrication of a honeycomb-like bimetallic SERS substrate for the detection of triphenyltin chloride[J]. ANALYST,2021:8. |
| APA | Jiang, Shan.,Chang, Lin.,Luo, Jie.,Zhang, Jianfa.,Liu, Xiaohong.,...&Zhang, Wei.(2021).Fabrication of a honeycomb-like bimetallic SERS substrate for the detection of triphenyltin chloride.ANALYST,8. |
| MLA | Jiang, Shan,et al."Fabrication of a honeycomb-like bimetallic SERS substrate for the detection of triphenyltin chloride".ANALYST (2021):8. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
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