Two-body dissociation of C3H4 isomers investigated by 50 keV/u Ne8+ impact
文献类型：期刊论文
| 作者 | Li, Yutian2; Xu, Shenyue2 ; Guo, Dalong1; Jia, Shaokui2; Jiang, Xiaojuan2; Zhu, Xiaolong1; Ma, Xinwen1
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| 刊名 | JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2019-04-14 |
| 卷号 | 150期号:14页码:7 |
| ISSN号 | 0021-9606 |
| DOI | 10.1063/1.5097413 |
| 通讯作者 | Xu, Shenyue(xushenyue@xjtu.edu.cn) |
| 英文摘要 | The fragmentation of two isomers of C3H4, propyne (CH3CCH) and allene (CH2CCH2), is investigated by 50 keV/u Ne8+ impact. Obvious isomer effects are observed by comparing the time-of-flight spectra generated from the two isomers. Six two-body fragmentation channels of C3H42+ dications are identified for each isomer. CH2+ + C2H2+ is found to be the most favored CC bond breaking channel for both isomers, indicating that CH3CCH2+ intends to rearrange to the structure containing the CH2 group before fragmentation. For CH bond breaking channels, it is found that the CH3CCH which contains a CH3 group is more efficient for H-2(+) and H-3(+) ejection. In addition, twobody dissociation channels of C3H43+ trications are identified. While the H+ + C3H32+ channel is observed in the fragmentation of both isomers, the H+ + C3H32+ channel only occurs in the fragmentation of CH3CCH3+. For CH2CCH 3+ 2, the peak and shoulder structures in the kinetic energy release spectrum of the H+ + C3H32+ channel are attributed to different geometries of the C3H 2+ 3 product. |
| WOS关键词 | MOMENTUM SPECTROSCOPY ; RECOIL-ION ; FRAGMENTATION |
| 资助项目 | National Natural Science Foundation of China[11674332] ; National Natural Science Foundation of China[U1432122] ; National Key Research and Development Program of China[2017YFA0402300] ; China Postdoctoral Science Foundation[2017M613100] ; Fundamental Research Funds for the Central Universities of China |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000464451300031 |
| 出版者 | AMER INST PHYSICS |
| 资助机构 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; China Postdoctoral Science Foundation ; Fundamental Research Funds for the Central Universities of China |
| 源URL | [http://119.78.100.186/handle/113462/133778]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Xu, Shenyue |
| 作者单位 | 1.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Gansu, Peoples R China 2.Xi An Jiao Tong Univ, Sch Sci, Xian 710049, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yutian,Xu, Shenyue,Guo, Dalong,et al. Two-body dissociation of C3H4 isomers investigated by 50 keV/u Ne8+ impact[J]. JOURNAL OF CHEMICAL PHYSICS,2019,150(14):7. |
| APA | Li, Yutian.,Xu, Shenyue.,Guo, Dalong.,Jia, Shaokui.,Jiang, Xiaojuan.,...&Ma, Xinwen.(2019).Two-body dissociation of C3H4 isomers investigated by 50 keV/u Ne8+ impact.JOURNAL OF CHEMICAL PHYSICS,150(14),7. |
| MLA | Li, Yutian,et al."Two-body dissociation of C3H4 isomers investigated by 50 keV/u Ne8+ impact".JOURNAL OF CHEMICAL PHYSICS 150.14(2019):7. |
入库方式： OAI收割
来源：近代物理研究所
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