MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution
文献类型：期刊论文
| 作者 | Hu, Liuyong2; Xiao, Runshi2; Wang, Xia2; Wang, Xiaosi1; Wang, Canglong3 ; Wen, Jing2; Gu, Wenling1; Zhu, Chengzhou1
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| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2021-12-05 |
| 卷号 | 298页码:8 |
| 关键词 | Metal-organic frameworks Nonprecious metal catalysts Layered double hydroxide Oxygen evolution reaction |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2021.120599 |
| 通讯作者 | Wen, Jing(jing.wen@wit.edu.cn) ; Gu, Wenling(wlgu@mail.ccnu.edu.cn) ; Zhu, Chengzhou(czzhu@mail.ccnu.edu.cn) |
| 英文摘要 | Metal-organic framework (MOF)-based materials are regarded as potential electrocatalysts for oxygen evolution reaction (OER) resulting from the abundant pore structures, large surface area and atomically dispersed metal centers, while their coordinately saturated metal nodes are inert to electrocatalysis. In this work, creating active sites while accelerating charge transport is proposed to improve the OER properties of MOF-derived layered double hydroxides (MLDH). By using multifunctional Ti3C2 MXene as support and post-treating MOF with an etching-coprecipitating process, the resultant CoFe MLDH/Ti3C2 exhibits prominent OER performance with ultralow overpotentials of only 170 and 238 mV to achieve the current density of 10 and 100 mA/cm2, respectively. In addition, the experimental and theoretical calculation results prove the strong electronic interaction between CoFe MLDH and Ti3C2 MXene could modulate the binding strength of intermediates for OER. This work gives a direction to prepare MOF-based efficient catalysts and enhance the intrinsic activity of (oxy)hydroxidebased catalysts. |
| WOS关键词 | LAYERED DOUBLE HYDROXIDE ; HIGHLY EFFICIENT ; ELECTROCATALYSTS ; CATALYSTS ; SITES |
| 资助项目 | Wuhan Institute of Technology[19QD10] ; Natural Science Foundation of Hubei Province[2020CFB276] ; Fundamental Research Funds for the Central Universities[CCNU20QN007] ; Fundamental Research Funds for the Central Universities[CCNU20TS013] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000702284100006 |
| 出版者 | ELSEVIER |
| 资助机构 | Wuhan Institute of Technology ; Natural Science Foundation of Hubei Province ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://119.78.100.186/handle/113462/136288]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Wen, Jing; Gu, Wenling; Zhu, Chengzhou |
| 作者单位 | 1.Cent China Normal Univ, Coll Chem, Int Joint Res Ctr Intelligent Biosensing Technol, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China 2.Wuhan Inst Technol, Sch Mat Sci & Engn, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430205, Peoples R China 3.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Liuyong,Xiao, Runshi,Wang, Xia,et al. MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2021,298:8. |
| APA | Hu, Liuyong.,Xiao, Runshi.,Wang, Xia.,Wang, Xiaosi.,Wang, Canglong.,...&Zhu, Chengzhou.(2021).MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution.APPLIED CATALYSIS B-ENVIRONMENTAL,298,8. |
| MLA | Hu, Liuyong,et al."MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution".APPLIED CATALYSIS B-ENVIRONMENTAL 298(2021):8. |
入库方式： OAI收割
来源：近代物理研究所
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