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Spin-orbit splittings in the low-lying states of MoO molecule

文献类型：期刊论文

作者Zhang, Lei1,3,4; Zou, Wenli2,5; Yu, Yao1,3,4; Zhao, Dongmei1,4; Ma, Xinwen1,4; Yang, Jie1,4
刊名JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
出版日期2021-07-01
卷号269页码:7
ISSN号0022-4073
关键词MoO Low-lying states Spin-orbit splitting Laser-induced fluorescence (LIF) Ab initio calculation
DOI10.1016/j.jqsrt.2021.107690
通讯作者Yang, Jie(jie.yang@impcas.ac.cn)
英文摘要The laser-induced fluorescence (LIF) excitation spectra and single vibronic level (SVL) emission spectra of the jet-cooled molybdenum monoxide (MoO) molecule in the gas phase have been investigated in the range of 16,500-23,200 cm(-1). Totally 11 rotationally resolved excitation spectra have been observed, and the rotational constants in 10 upper excited states and 4 lower spin-orbit components of the ground X (5)Pi state have been obtained. In addition, 10 spin-orbit components in the ground X (5)Pi state, the first and second excited states a (3)Sigma(-) and b (3)Delta, have been identified in the emission spectra. Ab initio calculations have been performed and used to identify the observed low-lying states. (c) 2021 Elsevier Ltd. All rights reserved.
WOS关键词INDUCED FLUORESCENCE SPECTROSCOPY ; ELECTRONIC-STRUCTURE ; PHOTOELECTRON-SPECTROSCOPY ; ROTATIONAL ANALYSIS ; ABSORPTION-SPECTRA ; INFRARED-SPECTRA ; TRANSITION ; OXIDES ; MOLYBDENUM ; CRO
资助项目National Key R&D Program of China[2017YFA0402300] ; National Natural Science Foundation of China[U1832175] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB21030900] ; Double FirstClass University Construction Project of Northwest University
WOS研究方向Optics ; Spectroscopy
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000654343500006
资助机构National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Double FirstClass University Construction Project of Northwest University
源URL[http://119.78.100.186/handle/113462/137160]  
专题中国科学院近代物理研究所
通讯作者Yang, Jie
作者单位1.Chinese Acad Sci, Inst Modern Phys, CAS Key Lab High Precis Nucl Spect, Lanzhou 73000, Peoples R China
2.Northwest Univ, Inst Modern Phys, Xian 710127, Shaanxi, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China
5.Shaanxi Key Lab Theoret Phys Frontiers, Xian 710127, Shaanxi, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Lei,Zou, Wenli,Yu, Yao,et al. Spin-orbit splittings in the low-lying states of MoO molecule[J]. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER,2021,269:7.
APA Zhang, Lei,Zou, Wenli,Yu, Yao,Zhao, Dongmei,Ma, Xinwen,&Yang, Jie.(2021).Spin-orbit splittings in the low-lying states of MoO molecule.JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER,269,7.
MLA Zhang, Lei,et al."Spin-orbit splittings in the low-lying states of MoO molecule".JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER 269(2021):7.

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来源：近代物理研究所

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