Construction of Position-Controllable Graphene Bubbles in Liquid Nitrogen with Assistance of Low-Power Laser
文献类型：期刊论文
| 作者 | Zhang, Xin1 ; Zhang, Haojie2; Cao, Shiwei3; Zhang, Ning4; Jin, Bo1; Zong, Zewen1; Li, Zhan1; Chen, Ximeng1
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| 刊名 | ACS APPLIED MATERIALS & INTERFACES
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| 出版日期 | 2020-12-16 |
| 卷号 | 12期号:50页码:56260-56268 |
| ISSN号 | 1944-8244 |
| 关键词 | liquid nitrogen laser graphene bubbles molecular dynamics position controllable |
| DOI | 10.1021/acsami.0c14857 |
| 通讯作者 | Li, Zhan(lizhancg@licp.cas.cn) ; Chen, Ximeng(chenxm@lzu.edu.cn) |
| 英文摘要 | Graphene bubbles (GBs) are of significant interest owing to their distinguished electrical, optical, and magnetic properties. GBs can also serve as high-pressure reaction vessels to numerous chemical reactions. However, previous strategies to produce GBs are relatively elaborate and random. Therefore, their potential applications are severely restricted. Here, a facile and effective protocol is proposed to construct position-controllable GBs in liquid nitrogen (LN) with the assistance of laser and graphene wrinkles. Specifically, a film of graphene mounted on a SiO2 substrate (G@SiO2) is subjected to irradiation by a low-power laser in LN and then many GBs emerge from the surface of G@SiO2. Most impressively, the domain where GBs arise is the position of the laser beam spot. Hence, we demonstrated that the high collimation of laser facilitates the position definition of GBs. The microscopic results indicate that some GBs split into three parts when they were subjected to irradiation by an electron. Meanwhile, some GBs degenerate into pores with a diameter of 500 nm when they are exposed to air. To grasp the properties of GBs in depth, the molecular dynamics (MD) simulations are performed, and the corresponding results indicate that temperature has very little impact on the GBs' shape. A phase transition process of the substance inside GBs is also revealed. Moreover, a two-dimensional (2D) solid nitrogen is discovered by MD simulations. The simplicity of our protocol paves the way to engineer high-pressure microreaction vessels and fabricate porous graphene membranes. |
| WOS关键词 | GAS-TRANSPORT ; NANOBUBBLES ; DYNAMICS ; INTERFACES |
| 资助项目 | National Natural Science Foundation of China[21974146] ; National Natural Science Foundation of China[21675164] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000600202300069 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://119.78.100.186/handle/113462/138160]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Li, Zhan; Chen, Ximeng |
| 作者单位 | 1.Lanzhou Univ, Sch Nucl Sci & Technol, Lanzhou 730000, Peoples R China 2.Nankai Univ, Sch Phys, Tianjin 300071, Peoples R China 3.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China 4.Peking Univ, Sch Phys, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xin,Zhang, Haojie,Cao, Shiwei,et al. Construction of Position-Controllable Graphene Bubbles in Liquid Nitrogen with Assistance of Low-Power Laser[J]. ACS APPLIED MATERIALS & INTERFACES,2020,12(50):56260-56268. |
| APA | Zhang, Xin.,Zhang, Haojie.,Cao, Shiwei.,Zhang, Ning.,Jin, Bo.,...&Chen, Ximeng.(2020).Construction of Position-Controllable Graphene Bubbles in Liquid Nitrogen with Assistance of Low-Power Laser.ACS APPLIED MATERIALS & INTERFACES,12(50),56260-56268. |
| MLA | Zhang, Xin,et al."Construction of Position-Controllable Graphene Bubbles in Liquid Nitrogen with Assistance of Low-Power Laser".ACS APPLIED MATERIALS & INTERFACES 12.50(2020):56260-56268. |
入库方式： OAI收割
来源：近代物理研究所
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