The Laser-Induced Fluorescence Spectrum of Gold Monoxide (AuO) : b(4)Pi(3/2) - X-2 Pi(3/2) Transition
文献类型：期刊论文
| 作者 | Xiang Qian-lan1,3; Yang Jie2 ; Hua Xue-xia1; Zhang Ji-cai2; Ma Xin-wen2
|
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2020-06-01 |
| 卷号 | 40期号:6页码:1747-1750 |
| 关键词 | AuO Laser-induced fluorescence (LIF) Electronic spectrum |
| ISSN号 | 1000-0593 |
| DOI | 10.3964/j.issn.1000-0593(2020)06-1747-04 |
| 通讯作者 | Xiang Qian-lan(xiangqianlan692@sohu.com) |
| 英文摘要 | Studying Au-O bond can provide an insight into the rapidly expanding field of gold chemistry. AuO is the simplest model containing Au-O bond. So, it is of great scientific significance to study the electronic structure of gold oxide molecule. Laser induced fluorescence spectroscopy is an effective means to study molecular structures and chemical bonds. In this paper laser ablation combined with ultrasonic jet technology was used to produce gas phase gold monoxide, and the electronic spectrum of the gaseous gold monoxide molecule (AuO) had been investigated in the range of 16 500 similar to 18 500 cm(-1) using laser induced fluorescence spectroscopy. The ablation laser (Leibao Dawa-300) sputtered pure gold target (99. 9%) which was controlled by a vacuum motor for rotation to produce Au atoms. The pure high pressure O-2 was injected into the vacuum chamber through a molecular beam pulse valve (Parker, General Valve, series 9) to react with the gold vapor to form AuO. A dye laser (Sirah, Cobra-Stretch) was pumped by Nd YAG laser (Continuum Surelite II-10) and the output of the pulsed dye laser (linewidth 0.05 cm(-1), pulse duration 5 ns, energy 0.1 mJ . pulse(-1)) was introduced into the vacuum chamber to excite AuO. The fluorescence from the excited AuO radical was imaged through appropriate low-pass cutoff filters into a photomultiplier tube (PMT) detector (EMI, ET9202QB). Pulsed analog signals from the PMT were converted into digital signals by a fast digital oscilloscope card (Picoscope 6404C, 500 MHz, 14 bits) and recorded by a data acquisition program based on LabVIEW of our own. The detected bands with band heads at 17 152. 94, 17 552. 17, 17 932. 78 and 18 291. 62 cm(-1) were attributed to b(4)Pi(3/2) (v'=0 1, 2, 3) - X-2 Pi(3/2) (v '' = 0) transitions. The molecular constants including rotational constants and centrifugal distortion constants were determined by analyzing the rotationally resolved spectra. The possible electronic configuration of the excited state is 1 sigma(2)1 pi(4)1 delta(4)2 sigma(1)2 pi(3)3 sigma*(1). |
| WOS关键词 | ABSORPTION SPECTROSCOPY ; IDENTIFICATION |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000545315300015 |
| 出版者 | OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS |
| 源URL | [http://119.78.100.186/handle/113462/140332]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Xiang Qian-lan |
| 作者单位 | 1.Chinese Acad Sci, Ion Beam & Opt Phys Joint Lab Xianyang Normal Uni, Xianyang 712000, Peoples R China 2.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China 3.Xi An Jiao Tong Univ, Dept Appl Phys, Xian 710049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang Qian-lan,Yang Jie,Hua Xue-xia,et al. The Laser-Induced Fluorescence Spectrum of Gold Monoxide (AuO) : b(4)Pi(3/2) - X-2 Pi(3/2) Transition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2020,40(6):1747-1750. |
| APA | Xiang Qian-lan,Yang Jie,Hua Xue-xia,Zhang Ji-cai,&Ma Xin-wen.(2020).The Laser-Induced Fluorescence Spectrum of Gold Monoxide (AuO) : b(4)Pi(3/2) - X-2 Pi(3/2) Transition.SPECTROSCOPY AND SPECTRAL ANALYSIS,40(6),1747-1750. |
| MLA | Xiang Qian-lan,et al."The Laser-Induced Fluorescence Spectrum of Gold Monoxide (AuO) : b(4)Pi(3/2) - X-2 Pi(3/2) Transition".SPECTROSCOPY AND SPECTRAL ANALYSIS 40.6(2020):1747-1750. |
入库方式： OAI收割
来源：近代物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。