Improved efficiency of liquid-phase shear exfoliation of expanded graphite with mica plates as bifunctional additives
文献类型：期刊论文
| 作者 | Liang, Bin2,3,4; Liu, Kangwei1,2,3; Liu, Peng1,2,3; Zhao, Guangyao1,2,3; Pan, Weisheng1,2,3; Hu, Shengyu2,3; Cui, Yuanzheng2,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2021-12-14 |
| 卷号 | 9期号:48页码:27586-27595 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/d1ta07915h |
| 通讯作者 | Liang, Bin(bliang@imr.ac.cn) |
| 英文摘要 | Liquid-phase shear exfoliation (LPSE) is a potential method of large-scale production of good-quality graphene. Obtaining few-layer (<10) graphene with large lateral sizes and high yields remains a challenging issue. Here, we report an improved LPSE processing method involving the addition of mica plates, which serve as bifunctional agents. With the addition of 100 g L-1 of mica, the LPSE (9000 rpm/0.24 mm/1 h) of expanded graphite offers similar to 100% few-layer graphene with average lateral sizes (ALSs) of similar to 2.8 mu m and yields of up to 27% (the highest ever reported). The graphene produced by LPSE without any additives, however, contains only similar to 77% few-layer nanosheets, and has ALSs of similar to 1.3 mu m and yields of 8%. Significantly, the addition of SiO2 microspheres as a comparison has almost no influence on the LPSE. The mica plates control the vector of fluids in LPSE and guide the oriented arrangement of the layered materials (e.g., expanded graphite), leading to significantly improved LPSE efficiency. 2D transition metal dichalcogenides (TMDs) with improved yields were also successfully prepared using LPSE with the addition of mica. |
| 资助项目 | National Natural Science Foundation of China[51902173] ; China Postdoctoral Science Foundation[2019T120084] ; China Postdoctoral Science Foundation[2018M640123] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000724955200001 |
| 资助机构 | National Natural Science Foundation of China ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.imr.ac.cn/handle/321006/167538]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liang, Bin |
| 作者单位 | 1.Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China 2.Tsinghua Univ, Shenzhen Geim Graphene Ctr, Tsinghua Shenzhen Int Grad Sch, Shenzhen Key Lab Power Battery Safety, Shenzhen 518055, Peoples R China 3.Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Inst Mat Res, Shenzhen 518055, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Bin,Liu, Kangwei,Liu, Peng,et al. Improved efficiency of liquid-phase shear exfoliation of expanded graphite with mica plates as bifunctional additives[J]. JOURNAL OF MATERIALS CHEMISTRY A,2021,9(48):27586-27595. |
| APA | Liang, Bin.,Liu, Kangwei.,Liu, Peng.,Zhao, Guangyao.,Pan, Weisheng.,...&Cui, Yuanzheng.(2021).Improved efficiency of liquid-phase shear exfoliation of expanded graphite with mica plates as bifunctional additives.JOURNAL OF MATERIALS CHEMISTRY A,9(48),27586-27595. |
| MLA | Liang, Bin,et al."Improved efficiency of liquid-phase shear exfoliation of expanded graphite with mica plates as bifunctional additives".JOURNAL OF MATERIALS CHEMISTRY A 9.48(2021):27586-27595. |
入库方式： OAI收割
来源：金属研究所
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