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A transparent electrode with water-oxidizing activity

文献类型：期刊论文

作者Azadi, Gouhar; Bagheri, Robabeh16; Bikas, Rahman1; Mousazade, Younes; Cui, Junfeng2,3; Song, Zhenlun16; Kinzhybalo, Vasyl4; Shen, Jian-Ren; Allakhverdiev, Suleyman I.; Najafpour, Mohammad Mahdi6,7
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
出版日期2018
卷号43期号:51页码:22896-22904
关键词Water oxidation Hydrogen production Fluorine-doped tin oxide Catalyst
ISSN号0360-3199
DOI10.1016/j.ijhydene.2018.10.146
文献子类Article
英文摘要Hydrogen production by water splitting is a promising method to store energy. Water-oxidation reaction is a bottleneck in water-splitting systems. Herein, a mononuclear nickel(II) phosphine complex with 1,2-bis(dicyclohexylphosphino)ethane ligand, was synthesized and characterized by X-ray crystallography method. The water-oxidizing catalyst under the electrochemical condition was studied. The role of Ni compound for the water-oxidation reaction on the surface of fluorine-doped tin oxide as one of the true catalysts was investigated by the electrochemical methods and Scanning Electron Microscopy coupled with Energy Dispersive X-ray (SEM/EDX) Spectroscopy. The big ligand around the Ni ion causes a very small size of Ni-based particles on the surface of the electrode, which are the active catalysts for the water-oxidation reaction. Such small nanosized Ni-based compounds are transparent and have no effect on the transparency of the obtained fluorine-doped tin oxide. Thus, it is a promising method to synthesize a transparent fluorine-doped tin oxide with water-oxidizing activity. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
学科主题Chemistry, Physical ; Electrochemistry ; Energy & Fuels
出版地OXFORD
电子版国际标准刊号1879-3487
WOS关键词OXIDATION CATALYSTS ; SINGLE-CRYSTALS ; MANGANESE OXIDE ; NICKEL ; COMPLEX ; EFFICIENT ; TETRAFLUOROBORATE ; ELECTROCATALYSTS ; PALLADIUM ; INSIGHTS
语种英语
WOS记录号WOS:000453642500011
出版者PERGAMON-ELSEVIER SCIENCE LTD
资助机构Iran National Science Foundation (INSF)Iran National Science Foundation (INSF) [95007330] ; Institute for Advanced Studies in Basic Sciences, Imam Khomeini International University ; Polish Academy of Science [24000018] ; JSPS, MEXT, JapanMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [24000018] ; Russian Science FoundationRussian Science Foundation (RSF) [14-14-00039]
源URL[http://ir.ibcas.ac.cn/handle/2S10CLM1/20616]  
专题中科院光生物学重点实验室
作者单位1.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Surface Dept, Surface Protect Res Grp, 519 Zhuangshi Rd, Ningbo 315201, Zhejiang, Peoples R China
2.Imam Khomeini Int Univ, Dept Chem, Fac Sci, Qazvin 3414896818, Iran
3.Dalian Univ Technol, Key Lab Precis & Nontradit Machining Technol, Minist Educ, Dalian 116024, Peoples R China
4.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
5.IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran
6.IASBS, Ctr Climate Change & Global Warming, Zanjan 4513766731, Iran
7.Allakhverdiev, Suleyman I.] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia
8.Allakhverdiev, Suleyman I.] Moscow MV Lomonosov State Univ, Dept Plant Physiol, Fac Biol, Leninskie Gory 1-12, Moscow 119991, Russia
9.Allakhverdiev, Suleyman I.] Russian Acad Sci, Inst Basic Biol Problems, Pushchino 142290, Moscow Region, Russia
10.Allakhverdiev, Suleyman I.] Azerbaijan Natl Acad Sci, Inst Mol Biol & Biotechnol, Bionanotechnol Lab, Matbuat Ave 2a, Baku 1073, Azerbaijan
推荐引用方式
GB/T 7714		 Azadi, Gouhar,Bagheri, Robabeh,Bikas, Rahman,et al. A transparent electrode with water-oxidizing activity[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2018,43(51):22896-22904.
APA Azadi, Gouhar.,Bagheri, Robabeh.,Bikas, Rahman.,Mousazade, Younes.,Cui, Junfeng.,...&Najafpour, Mohammad Mahdi.(2018).A transparent electrode with water-oxidizing activity.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,43(51),22896-22904.
MLA Azadi, Gouhar,et al."A transparent electrode with water-oxidizing activity".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 43.51(2018):22896-22904.

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来源：植物研究所

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