中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Inhibition performance of 4-mercaptopyridine toward the corrosion of carbon steel in hydrochloric acid solution

文献类型:期刊论文

作者Han, Peng3; Sun, Xin2,4; Zhang, Buyun3; Chang, Zhixuan3; Shen, Ji3; Wang, Qian3; Tian, Huiwen2,4; Zhang, Xuanwei1
刊名JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
出版日期2021-12-15
页码15
ISSN号0169-4243
关键词Surfactant interface electrochemical bilayer simulation
DOI10.1080/01694243.2021.2008122
通讯作者Han, Peng(hanpeng972@163.com)
英文摘要The corrosion inhibition performance of 4-mercaptopyridine (4MP) as corrosion inhibitor for A(3) steel has been studied using electrochemical method. The maximum inhibition efficiency value is 96.3% at 0.25 h and the inhibition efficiency is higher than 89.4% after immersion of the electrode in hydrochloric acid solution for 33 h. XPS results and frontier orbital calculation results show 4MP molecule adsorb on steel surface mainly through sulfhydryl groups and N atoms. Molecular dynamic simulation results show that an inhibitor layer formed on metal surface in the beginning while the inhibitor film changes from monolayer type to bilayer type with the increasing of time, the corrosion resistance and the corrosion inhibition efficiency of the adsorbed inhibitor film was improved. The phenomenon supplies new perspective for the designing of the molecules used as inhibitors, which is beneficial for the improvement of the adsorption durability of the potential used inhibitor after long period of immersion in acid medium.
资助项目Fundamental Research Funds for the Central Universities[51701234] ; Fundamental Research Funds for the Central Universities and Training Program of Innovation and Entrepreneurship for Undergraduates[2020XJJD01]
WOS研究方向Engineering ; Materials Science ; Mechanics
语种英语
出版者TAYLOR & FRANCIS LTD
WOS记录号WOS:000731276300001
源URL[http://ir.qdio.ac.cn/handle/337002/177524]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Han, Peng
作者单位1.Guangdong Maritime Silk Rd Museum, Guangzhou, Guangdong, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao, Peoples R China
3.China Univ Min & Technol Beijing, Dept Mat Sci & Engn, Beijing, Peoples R China
4.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao, Peoples R China
推荐引用方式
GB/T 7714
Han, Peng,Sun, Xin,Zhang, Buyun,et al. Inhibition performance of 4-mercaptopyridine toward the corrosion of carbon steel in hydrochloric acid solution[J]. JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY,2021:15.
APA Han, Peng.,Sun, Xin.,Zhang, Buyun.,Chang, Zhixuan.,Shen, Ji.,...&Zhang, Xuanwei.(2021).Inhibition performance of 4-mercaptopyridine toward the corrosion of carbon steel in hydrochloric acid solution.JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY,15.
MLA Han, Peng,et al."Inhibition performance of 4-mercaptopyridine toward the corrosion of carbon steel in hydrochloric acid solution".JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY (2021):15.

入库方式: OAI收割

来源:海洋研究所

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