中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics

文献类型:期刊论文

作者Zhang, Bo; Zhao, Qing; Chang, Aimin; Li, Yiyu; Liu, Yin; Wu, Yiquan
刊名Journal of the European Ceramic Society
出版日期2014
卷号34期号:12页码:2989-2995
关键词Spark Plasma Sintering Ntc Thermistors Spinel Perovskite Electrical Properties
ISSN号9552219
DOI10.1016/j.jeurceramsoc.2014.03.025
英文摘要

New high temperature negative temperature coefficient (NTC) thermistor ceramics based on a xMgAl(2)O(4)-(1-x)YCr0.5Mn0.5O3 (x = 0.1, 0.4, 0.6) composite system have been successfully fabricated through spark plasma sintering (SPS) with a low sintering temperature and a short sintering period. The X-ray diffraction analysis indicates that the SPS-sintered composite ceramics consist of a cubic spinel MgAl2O4 phase and an orthorhombic perovskite YCr0.5Mn0.5O3 phase isomorphic to YCr0.3. The SPS-sintered composite ceramics have high relative density ranging from 94.1 to 97.4% of the theoretical density. X-ray photoelectron spectroscopy analysis corroborates the presence of Cr3+, Cr4+, Mn3+, and Mn4+ ions on lattice sites, which may result in the hopping conduction. The obtained p(25), B25-150, and B700-1000 of the SPS-sintered composite NTC thermistors are in the range of 1.53 x 10(6)-9.92 x 10(9) Omega cm, 3380-5172 K, and 7239-9543 K, respectively. These values can be tuned by adjusting the MgAl2O4 concentration.

WOS记录号WOS:000337863800015
公开日期2014-11-11
源URL[http://ir.xjipc.cas.cn/handle/365002/3736]  
专题新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室
新疆理化技术研究所_材料物理与化学研究室
通讯作者Chang, Aimin
作者单位1.Alfred Univ, New York State Coll Ceram, Kazuo Inamori Sch Engn, Alfred, NY 14802 USA
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Bo,Zhao, Qing,Chang, Aimin,et al. Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics[J]. Journal of the European Ceramic Society,2014,34(12):2989-2995.
APA Zhang, Bo,Zhao, Qing,Chang, Aimin,Li, Yiyu,Liu, Yin,&Wu, Yiquan.(2014).Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics.Journal of the European Ceramic Society,34(12),2989-2995.
MLA Zhang, Bo,et al."Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics".Journal of the European Ceramic Society 34.12(2014):2989-2995.

入库方式: OAI收割

来源:新疆理化技术研究所

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