Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics
文献类型:期刊论文
作者 | Zhang, Bo![]() ![]() |
刊名 | Journal of the European Ceramic Society
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出版日期 | 2014 |
卷号 | 34期号:12页码:2989-2995 |
关键词 | Spark Plasma Sintering Ntc Thermistors Spinel Perovskite Electrical Properties |
ISSN号 | 9552219 |
DOI | 10.1016/j.jeurceramsoc.2014.03.025 |
英文摘要 | New high temperature negative temperature coefficient (NTC) thermistor ceramics based on a xMgAl(2)O(4)-(1-x)YCr0.5Mn0.5O3 (x = 0.1, 0.4, 0.6) composite system have been successfully fabricated through spark plasma sintering (SPS) with a low sintering temperature and a short sintering period. The X-ray diffraction analysis indicates that the SPS-sintered composite ceramics consist of a cubic spinel MgAl2O4 phase and an orthorhombic perovskite YCr0.5Mn0.5O3 phase isomorphic to YCr0.3. The SPS-sintered composite ceramics have high relative density ranging from 94.1 to 97.4% of the theoretical density. X-ray photoelectron spectroscopy analysis corroborates the presence of Cr3+, Cr4+, Mn3+, and Mn4+ ions on lattice sites, which may result in the hopping conduction. The obtained p(25), B25-150, and B700-1000 of the SPS-sintered composite NTC thermistors are in the range of 1.53 x 10(6)-9.92 x 10(9) Omega cm, 3380-5172 K, and 7239-9543 K, respectively. These values can be tuned by adjusting the MgAl2O4 concentration. |
WOS记录号 | WOS:000337863800015 |
公开日期 | 2014-11-11 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/3736] ![]() |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Chang, Aimin |
作者单位 | 1.Alfred Univ, New York State Coll Ceram, Kazuo Inamori Sch Engn, Alfred, NY 14802 USA 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Bo,Zhao, Qing,Chang, Aimin,et al. Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics[J]. Journal of the European Ceramic Society,2014,34(12):2989-2995. |
APA | Zhang, Bo,Zhao, Qing,Chang, Aimin,Li, Yiyu,Liu, Yin,&Wu, Yiquan.(2014).Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics.Journal of the European Ceramic Society,34(12),2989-2995. |
MLA | Zhang, Bo,et al."Spark plasma sintering of MgAl2O4-YCr0.5Mn0.5O3 composite NTC ceramics".Journal of the European Ceramic Society 34.12(2014):2989-2995. |
入库方式: OAI收割
来源:新疆理化技术研究所
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