alpha-SnF2: A UV Birefringent Material with Large Birefringence and Easy Crystal Growth
文献类型：期刊论文
| 作者 | Guo, JY (Guo, Jingyu) [1] , [2]; Tudi, A (Tudi, Abudukadi) [1] , [2]; Han, SJ (Han, Shujuan) [1] , [2] ; Yang, ZH (Yang, Zhihua) [1] , [2]; Pan, SL (Pan, Shilie) [1] , [2]
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| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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| 出版日期 | 2018 |
| 卷号 | 60期号:7页码:3540-3544 |
| 关键词 | band gaps birefringent materials slow evaporation stannous fluoride stereochemical-activity lone pair |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202014279 |
| 英文摘要 | The simple binary fluoride alpha-SnF2 is shown to be an excellent birefringent material with outstanding birefringence, about 14 times that of MgF2. Furthermore, it exhibits a shorter UV cutoff edge and easy crystal growth at ambient temperature compared to YVO4 and TiO2. A novel theoretical calculation mode was established to analyze the stereochemical-activity lone-pair (SCALP) contribution to the birefringence (SCB) based on the SCALP ' s strength and arrangement, and it was found that the large birefringence of alpha-SnF2 mainly benefits from well-aligned [SnF5] polyhedra with a strong SCALP. The exploration of the alpha-SnF2 birefringent crystal points out the direction of the future search for excellent birefringent materials. |
| WOS记录号 | WOS:000600456000001 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/8142]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, JY ,Tudi, A ,Han, SJ ,et al. alpha-SnF2: A UV Birefringent Material with Large Birefringence and Easy Crystal Growth[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,60(7):3540-3544. |
| APA | Guo, JY ,Tudi, A ,Han, SJ ,Yang, ZH ,&Pan, SL .(2018).alpha-SnF2: A UV Birefringent Material with Large Birefringence and Easy Crystal Growth.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,60(7),3540-3544. |
| MLA | Guo, JY ,et al."alpha-SnF2: A UV Birefringent Material with Large Birefringence and Easy Crystal Growth".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 60.7(2018):3540-3544. |
入库方式： OAI收割
来源：新疆理化技术研究所
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