Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11
文献类型：期刊论文
| 作者 | Su, X (Su, Xin); Yang, ZH (Yang, Zhihua) ; Lee, MH (Lee, Ming-Hsien); Pan, SL (Pan, Shilie); Wang, Y (Wang, Ying); Fan, XY (Fan, Xiaoyun); Huang, ZJ (Huang, Zhenjun); Zhang, BB (Zhang, Bingbing)
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| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
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| 出版日期 | 2015 |
| 卷号 | 17期号:7页码:5338-5344 |
| ISSN号 | 1463-9076 |
| DOI | 10.1039/c4cp04248d |
| 英文摘要 | A novel mechanism for the nonlinear optical (NLO) effects of vanadium borate crystals, Na3VO2B6O11 (NVB), with distorted VO4 groups was investigated. A comprehensive analysis of the structure-property relationship was performed by combining the experimental measurements, the electronic structures calculations, the SHG-weighted electron density and the real-space atom-contribution analysis to yield the linear and nonlinear optical properties. The contribution of a (VO4)(3-) anionic group to the second harmonic generation (SHG) response was more pronounced than that of the (BO3)(3-) anionic group, which plays a virtual role in the SHG effects in NVB. The anionic (BO3)(3-) groups make dominant contributions to the birefringence, whereas the contribution of the V5+ cations to these linear optical effects is negligible. |
| WOS记录号 | WOS:000349616400062 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/8188]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Yang, ZH (Yang, Zhihua) |
| 作者单位 | 1.Tamkang Univ, Dept Phys, Taipei 25137, Taiwan 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, X ,Yang, ZH ,Lee, MH ,et al. Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(7):5338-5344. |
| APA | Su, X .,Yang, ZH .,Lee, MH .,Pan, SL .,Wang, Y .,...&Zhang, BB .(2015).Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(7),5338-5344. |
| MLA | Su, X ,et al."Evidence of "new hot spots'' from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na3VO2B6O11".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.7(2015):5338-5344. |
入库方式： OAI收割
来源：新疆理化技术研究所
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