Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion
文献类型:期刊论文
作者 | Cheng, HH (Cheng, Huanhuan) [1] , [2]; Li, FM (Li, Fuming) [1] , [2]; Yang, ZH (Yang, Zhihua) [1] , [2]; Pan, SL (Pan, Shilie) [1] , [2] |
刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
出版日期 | 2022 |
卷号 | 61期号:10页码:1-10 |
ISSN号 | 1433-7851 |
关键词 | chromatic dispersion fluorooxoborates fourth harmonic generation functionalized chromophoren onlinear optical materials |
DOI | 10.1002/anie.202115669 |
英文摘要 | Exploring significant ultraviolet/deep-ultraviolet nonlinear optical (NLO) materials is hindered by rigorous and contradictory requirements, especially, possessing a moderate optical birefringence to meet phase-matching (PM). Except for suitable birefringence, small chromatic dispersion is also crucial to blue-shift the PM wavelength. Here, the introduction of a fluorinated tetrahedral boron-centred chromophore strategy was proposed to optimize the chromatic dispersion. Herein, the [BF4](-) unit with a large HOMO-LUMO band gap was introduced to the Na-B-O-F system and Na4B8O9F10 was designed and synthesized successfully for the first time. Na4B8O9F10 with an optimized chromatic dispersion can achieve a short second harmonic generation PM wavelength of 240 nm with a relatively small birefringence (0.036@1064 nm). Notably, Na4B8O9F10 is the first acentric crystal with [BF4](-) units among the reported metal-fluorooxoborate systems, involving isolated [BF4](-) and novel [B7O10F6](5-) fundamental building blocks. |
WOS记录号 | WOS:000744737100001 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/8180] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 |
通讯作者 | Yang, ZH (Yang, Zhihua) [1] , [2]; Pan, SL (Pan, Shilie) [1] , [2] |
作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Cheng, HH ,Li, FM ,Yang, ZH ,et al. Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022,61(10):1-10. |
APA | Cheng, HH ,Li, FM ,Yang, ZH ,&Pan, SL .(2022).Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,61(10),1-10. |
MLA | Cheng, HH ,et al."Na4B8O9F10: A Deep-Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase-Matching Wavelength Induced by Optimized Chromatic Dispersion".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61.10(2022):1-10. |
入库方式: OAI收割
来源:新疆理化技术研究所
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